Synthesis of a Redox-Active NNP-Type Pincer Ligand and Its Application to Electrocatalytic CO2 Reduction With First-Row Transition Metal Complexes

Synthesis of a Redox-Active NNP-Type Pincer Ligand and Its Application to Electrocatalytic CO2 Reduction With First-Row Transition Metal Complexes

We report the synthesis of a rigid phosphine-substituted, redox-active pincer ligand and its application to electrocatalytic CO2 reduction with first-row transition metal complexes. The tridentate ligand was prepared by Stille coupling of 2,8-dibromoquinoline and 2-(tributylstannyl)pyridine, followe...

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Bibliographic Details
Main Authors: Kallol Talukdar, Asala Issa, Jonah W. Jurss
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-05-01
Series:Frontiers in Chemistry
Subjects:
molecular catalyst
CO2 reduction
electrocatalysis
pincer ligand
first-row metals
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00330/full

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