Properties of Ion Complexes and Their Impact on Charge Transport in Organic Solvent-Based Electrolyte Solutions for Lithium Batteries: Insights from a Theoretical Perspective

• Main Authors: Jens Smiatek, Andreas Heuer, Martin Winter
• Format: Article
• Language: English
• Published: MDPI AG 2018-12-01
• Series: Batteries
• Subjects: electrolyte solutions; solvents and co-solvents; ion complex formation; ion correlation effects; molecular theory of solution; additives; lithium-ion batteries; lithium batteries
• Online Access: https://www.mdpi.com/2313-0105/4/4/62

Electrolyte formulations in standard lithium ion and lithium metal batteries are complex mixtures of various components. In this article, we review molecular key principles of ion complexes in multicomponent electrolyte solutions in regards of their influence on charge transport mechanisms. We outline basic concepts for the description of ion⁻solvent and ion⁻ion interactions, which can be used to rationalize recent experimental and numerical findings concerning modern electrolyte formulations. Furthermore, we discuss benefits and drawbacks of empirical concepts in comparison to molecular theories of solution for a more refined understanding of ion behavior in organic solvents. The outcomes of our discussion provide a rational for beneficial properties of ions, solvent, co-solvent and additive molecules, and highlight possible routes for further improvement of novel electrolyte solutions.