A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes

Unfilled and talc-filled Copolymer Polypropylene (PP) samples were produced through low-pressure foam-injection molding (FIM). The foaming stage of the process has been facilitated through a chemical blowing agent (C<sub>6</sub>H<sub>7</sub>NaO<sub>7</sub> and CaC...

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Main Authors: Gethin Llewelyn, Andrew Rees, Christian A. Griffiths, Martin Jacobi
Format: Article
Language:English
Published: MDPI AG 2019-11-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/11/11/1896
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spelling doaj-360b1848c72f417883ddb7acd0d23fc72020-11-25T02:21:51ZengMDPI AGPolymers2073-43602019-11-011111189610.3390/polym11111896polym11111896A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer PolypropylenesGethin Llewelyn0Andrew Rees1Christian A. Griffiths2Martin Jacobi3College of Engineering, Swansea University, Swansea, Wales SA1 8EN, UKCollege of Engineering, Swansea University, Swansea, Wales SA1 8EN, UKCollege of Engineering, Swansea University, Swansea, Wales SA1 8EN, UKTrexel GmbH, Ahlefelderstr. 64, D-51645 Gummersbach, GermanyUnfilled and talc-filled Copolymer Polypropylene (PP) samples were produced through low-pressure foam-injection molding (FIM). The foaming stage of the process has been facilitated through a chemical blowing agent (C<sub>6</sub>H<sub>7</sub>NaO<sub>7</sub> and CaCO<sub>3</sub> mixture), a physical blowing agent (supercritical N<sub>2</sub>) and a novel hybrid foaming (combination of said chemical and physical foaming agents). Three weight-saving levels were produced with the varying foaming methods and compared to conventional injection molding. The unfilled PP foams produced through chemical blowing agent exhibited the strongest mechanical characteristics due to larger skin wall thicknesses, while the weakest were that of the talc-filled PP through the hybrid foaming technique. However, the hybrid foaming produced superior microcellular foams for both PPs due to calcium carbonate (CaCO<sub>3</sub>) enhancing the nucleation phase.https://www.mdpi.com/2073-4360/11/11/1896polypropylenefoam-injection moldingtecocell<sup>®</sup>mucell<sup>®</sup>talccalcium carbonate
collection DOAJ
language English
format Article
sources DOAJ
author Gethin Llewelyn
Andrew Rees
Christian A. Griffiths
Martin Jacobi
spellingShingle Gethin Llewelyn
Andrew Rees
Christian A. Griffiths
Martin Jacobi
A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
Polymers
polypropylene
foam-injection molding
tecocell<sup>®</sup>
mucell<sup>®</sup>
talc
calcium carbonate
author_facet Gethin Llewelyn
Andrew Rees
Christian A. Griffiths
Martin Jacobi
author_sort Gethin Llewelyn
title A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
title_short A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
title_full A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
title_fullStr A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
title_full_unstemmed A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes
title_sort novel hybrid foaming method for low-pressure microcellular foam production of unfilled and talc-filled copolymer polypropylenes
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2019-11-01
description Unfilled and talc-filled Copolymer Polypropylene (PP) samples were produced through low-pressure foam-injection molding (FIM). The foaming stage of the process has been facilitated through a chemical blowing agent (C<sub>6</sub>H<sub>7</sub>NaO<sub>7</sub> and CaCO<sub>3</sub> mixture), a physical blowing agent (supercritical N<sub>2</sub>) and a novel hybrid foaming (combination of said chemical and physical foaming agents). Three weight-saving levels were produced with the varying foaming methods and compared to conventional injection molding. The unfilled PP foams produced through chemical blowing agent exhibited the strongest mechanical characteristics due to larger skin wall thicknesses, while the weakest were that of the talc-filled PP through the hybrid foaming technique. However, the hybrid foaming produced superior microcellular foams for both PPs due to calcium carbonate (CaCO<sub>3</sub>) enhancing the nucleation phase.
topic polypropylene
foam-injection molding
tecocell<sup>®</sup>
mucell<sup>®</sup>
talc
calcium carbonate
url https://www.mdpi.com/2073-4360/11/11/1896
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