[3]Ferrocenophan-1-one

The crystal structure of [3]ferrocenophan-1-one, [Fe(C13H12O)], has been redetermined at 150 K. The tethered cyclopentadienyl (Cp) rings are tilted by 9.39 (18)° and assume an eclipsed conformation. The 1-oxopropane-1,3-diyl bridge has a pseudo-envelope conformation with...

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Bibliographic Details
Main Authors: Petr Štěpnička, Ivana Císařová
Format: Article
Language:English
Published: International Union of Crystallography 2008-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808022927
Description
Summary:The crystal structure of [3]ferrocenophan-1-one, [Fe(C13H12O)], has been redetermined at 150 K. The tethered cyclopentadienyl (Cp) rings are tilted by 9.39 (18)° and assume an eclipsed conformation. The 1-oxopropane-1,3-diyl bridge has a pseudo-envelope conformation with the C=O group deviating by as much as 22.5 (2)° from coplanarity with its attached Cp ring.
ISSN:1600-5368