Development of Adhesive, Bioactive and Antibacterial Titania Sol-Gel Coating on Titanium Substrate by Dip-Coating Technique

• Main Authors: Diana Horkavcová, Quentin Doubet, Gisèle Laure Lecomte-Nana, Eva Jablonská, Aleš Helebrant
• Format: Article
• Language: English
• Published: MDPI AG 2021-02-01
• Series: Coatings
• Subjects: titania coating; sol-gel; dip-coating; silver; hydroxyapatite; tape test
• Online Access: https://www.mdpi.com/2079-6412/11/2/243

The sol-gel method provides a wide variety of applications in the medical field. One of these applications is the formation of coatings on the metal implants. The coatings containing specific additive can enhance or improve the existing surface properties of the substrate. In this work, titania sol-gel coatings were doped with two forms of silver (AgNO₃, Ag₃PO₄) and synthetic hydroxyapatite and applied on the titanium samples by dip-coating technique. After drying and slow firing, all coatings were characterized with scanning electron microscopy. Thin coatings were successfully prepared with excellent adhesion to the substrate (measured by ASTM D 3359-2), despite cracks. Coatings containing silver and hydroxyapatite demonstrated a 100% antibacterial effect against <i>Escherichia coli</i> after 24 h. The bioactivity of the coatings containing hydroxyapatite tested in modified simulated body fluid under static-dynamic conditions was confirmed by bone-like hydroxyapatite precipitation. To better understand the interaction of the coatings with simulated body fluid (SBF), changes of Ca²⁺ and (PO₄)³⁻ ions concentrations and pH values were studied.