Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV)
In the title complex, [Pt(N3)4(C10H9N3)], the PtIV ion is six-coordinated in a slightly distorted octahedral environment by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle between the p...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812011178 |
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doaj-38a6738800a545f8b0ab2360312610502020-11-25T01:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m447m44710.1107/S1600536812011178Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV)Kwang HaIn the title complex, [Pt(N3)4(C10H9N3)], the PtIV ion is six-coordinated in a slightly distorted octahedral environment by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 20.0 (3)°. The azide ligands are slightly bent [N—N—N = 173.5 (8)–175.1 (8)°]. In the crystal, the complex molecules are connected by N—H...N hydrogen bonds, forming a chain along the b axis. An intermolecular π–π interaction between the chains is also present, the ring centroid–centroid distance being 3.713 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812011178 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Kwang Ha |
| spellingShingle |
Kwang Ha Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) Acta Crystallographica Section E |
| author_facet |
Kwang Ha |
| author_sort |
Kwang Ha |
| title |
Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) |
| title_short |
Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) |
| title_full |
Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) |
| title_fullStr |
Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) |
| title_full_unstemmed |
Tetrakis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)platinum(IV) |
| title_sort |
tetrakis(azido-κn)(di-2-pyridylamine-κ2n2,n2′)platinum(iv) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-04-01 |
| description |
In the title complex, [Pt(N3)4(C10H9N3)], the PtIV ion is six-coordinated in a slightly distorted octahedral environment by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 20.0 (3)°. The azide ligands are slightly bent [N—N—N = 173.5 (8)–175.1 (8)°]. In the crystal, the complex molecules are connected by N—H...N hydrogen bonds, forming a chain along the b axis. An intermolecular π–π interaction between the chains is also present, the ring centroid–centroid distance being 3.713 (4) Å. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812011178 |
| work_keys_str_mv |
AT kwangha tetrakisazidoamp954ndi2pyridylamineamp9542n2n2amp8242platinumiv |
| _version_ |
1725124511863406592 |