(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine
In the title compound, C26H27ClN2O, the piperidine ring has a chair conformation and all of the ring substituents at Csp3 atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogo...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812028899 |
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doaj-39f0b6aa9054471a8fea65da4724486a2020-11-24T21:44:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2268o226810.1107/S1600536812028899(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imineChennan RamalinganSeik Weng NgEdward R. T. TiekinkIn the title compound, C26H27ClN2O, the piperidine ring has a chair conformation and all of the ring substituents at Csp3 atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogonal to the methoxy(methylidene)amine residue [N—O—C—C torsion angle = −87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supramolecular chains along [010] are sustained by C—H...π interactions in the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812028899 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink |
| spellingShingle |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink (4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine Acta Crystallographica Section E |
| author_facet |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink |
| author_sort |
Chennan Ramalingan |
| title |
(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_short |
(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_full |
(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_fullStr |
(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_full_unstemmed |
(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_sort |
(4e)-n-[(2-chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-07-01 |
| description |
In the title compound, C26H27ClN2O, the piperidine ring has a chair conformation and all of the ring substituents at Csp3 atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogonal to the methoxy(methylidene)amine residue [N—O—C—C torsion angle = −87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supramolecular chains along [010] are sustained by C—H...π interactions in the crystal packing. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812028899 |
| work_keys_str_mv |
AT chennanramalingan 4en2chlorophenylmethoxy13dimethyl26diphenylpiperidin4imine AT seikwengng 4en2chlorophenylmethoxy13dimethyl26diphenylpiperidin4imine AT edwardrttiekink 4en2chlorophenylmethoxy13dimethyl26diphenylpiperidin4imine |
| _version_ |
1725909732068163584 |