Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub>
In this study, Zeolitic Imidazolate Framework-8 (ZIF-8)-loaded UiO-66-NH<sub>2</sub> was synthesized, characterized, and analyzed for its potential to efficiently remove dyes. The selective adsorption on ZIF-8-loaded UiO-66-NH<sub>2</sub> or its parent MOFs (UiO-66-NH<sub&...
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doaj-3ad7e9e75f8c41dcb29d0df0cdb81adc2020-11-25T02:45:29ZengMDPI AGNanomaterials2079-49912019-09-0199128310.3390/nano9091283nano9091283Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub>Hao Zhang0Xiaobo Shi1Jialiang Li2Parveen Kumar3Bo Liu4School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, ChinaDepartment of Physics, Henan Finance University, Zhengzhou 450046, ChinaSchool of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, ChinaLaboratory of Functional Molecules and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, ChinaLaboratory of Functional Molecules and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, ChinaIn this study, Zeolitic Imidazolate Framework-8 (ZIF-8)-loaded UiO-66-NH<sub>2</sub> was synthesized, characterized, and analyzed for its potential to efficiently remove dyes. The selective adsorption on ZIF-8-loaded UiO-66-NH<sub>2</sub> or its parent MOFs (UiO-66-NH<sub>2</sub> and ZIF-8) in the mixed dyes solution was explored, including anionic dye (methyl orange (MO)) and cationic dyes (methylene blue (MB) and rhodamine B (RhB)). ZIF-8-loaded UiO-66-NH<sub>2</sub> displayed much better selectivity to MB than its parent MOFs. Adsorption capacity of ZIF-8-loaded UiO-66-NH<sub>2</sub> (173 mg/g) toward MB was found to be 215% higher than UiO-66-NH<sub>2</sub> (55 mg/g). A kinetics study based on adsorption data demonstrated that the adsorption process most closely matched with the model of pseudo-second-order kinetic and Langmuir isotherm. The adsorption was an exothermic and spontaneous physical process as revealed by the values of thermodynamic parameters. Furthermore, reusability of ZIF-8-loaded UiO-66-NH<sub>2</sub> was investigated and revealed the significant regeneration efficiency in adsorption capacity for MB even after four adsorption cycles. Experimental results proved that the interaction between ZIF-8-loaded UiO-66-NH<sub>2</sub> and MB was mainly affected by the mechanism, for instance, electrostatic interaction as well as π−π stacking interactions.https://www.mdpi.com/2079-4991/9/9/1283ZIF-8UiO-66-NH<sub>2</sub> compositesmetal-organic frameworksselective adsorption |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hao Zhang Xiaobo Shi Jialiang Li Parveen Kumar Bo Liu |
spellingShingle |
Hao Zhang Xiaobo Shi Jialiang Li Parveen Kumar Bo Liu Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> Nanomaterials ZIF-8 UiO-66-NH<sub>2</sub> composites metal-organic frameworks selective adsorption |
author_facet |
Hao Zhang Xiaobo Shi Jialiang Li Parveen Kumar Bo Liu |
author_sort |
Hao Zhang |
title |
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> |
title_short |
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> |
title_full |
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> |
title_fullStr |
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> |
title_full_unstemmed |
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH<sub>2</sub> |
title_sort |
selective dye adsorption by zeolitic imidazolate framework-8 loaded uio-66-nh<sub>2</sub> |
publisher |
MDPI AG |
series |
Nanomaterials |
issn |
2079-4991 |
publishDate |
2019-09-01 |
description |
In this study, Zeolitic Imidazolate Framework-8 (ZIF-8)-loaded UiO-66-NH<sub>2</sub> was synthesized, characterized, and analyzed for its potential to efficiently remove dyes. The selective adsorption on ZIF-8-loaded UiO-66-NH<sub>2</sub> or its parent MOFs (UiO-66-NH<sub>2</sub> and ZIF-8) in the mixed dyes solution was explored, including anionic dye (methyl orange (MO)) and cationic dyes (methylene blue (MB) and rhodamine B (RhB)). ZIF-8-loaded UiO-66-NH<sub>2</sub> displayed much better selectivity to MB than its parent MOFs. Adsorption capacity of ZIF-8-loaded UiO-66-NH<sub>2</sub> (173 mg/g) toward MB was found to be 215% higher than UiO-66-NH<sub>2</sub> (55 mg/g). A kinetics study based on adsorption data demonstrated that the adsorption process most closely matched with the model of pseudo-second-order kinetic and Langmuir isotherm. The adsorption was an exothermic and spontaneous physical process as revealed by the values of thermodynamic parameters. Furthermore, reusability of ZIF-8-loaded UiO-66-NH<sub>2</sub> was investigated and revealed the significant regeneration efficiency in adsorption capacity for MB even after four adsorption cycles. Experimental results proved that the interaction between ZIF-8-loaded UiO-66-NH<sub>2</sub> and MB was mainly affected by the mechanism, for instance, electrostatic interaction as well as π−π stacking interactions. |
topic |
ZIF-8 UiO-66-NH<sub>2</sub> composites metal-organic frameworks selective adsorption |
url |
https://www.mdpi.com/2079-4991/9/9/1283 |
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