The Enhanced Performance of N-Modified Activated Carbon Promoted with Ce in Selective Catalytic Reduction of NOx with NH<sub>3</sub>

The goal of the study was to modify activated carbon (AC) with nitrogen groups and ceria and to test the obtained materials in low temperature selective catalytic reduction of nitrogen oxides. For that purpose, the starting AC was oxidized with HNO<sub>3</sub> of various concentrations,...

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Bibliographic Details
Main Authors: Marwa Saad, Agnieszka Szymaszek, Anna Białas, Bogdan Samojeden, Monika Motak
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Catalysts
Subjects:
SCR
Online Access:https://www.mdpi.com/2073-4344/10/12/1423
Description
Summary:The goal of the study was to modify activated carbon (AC) with nitrogen groups and ceria and to test the obtained materials in low temperature selective catalytic reduction of nitrogen oxides. For that purpose, the starting AC was oxidized with HNO<sub>3</sub> of various concentrations, modified with urea and doped with 0.5 wt.% of Ce. It was observed that the increased concentration of acid influenced the catalytic activity, since textural and surface chemistry of activated carbon was changed. The most active sample was that modified with 14 M HNO<sub>3</sub> and it reached 96% of NO conversion at 300 °C. Additionally, the addition of Ce improved the catalytic performance of modified AC, and NO was reduced according to oxidation–reduction mechanism, characteristic for supported metal oxides. Nevertheless, the samples promoted with Ce emitted significantly higher amount of CO<sub>2</sub> comparing to the non-promoted ones.
ISSN:2073-4344