1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate

1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate

In the title compound, [Co(C13H22P)2]PF6, the CoIII atom is sandwiched between two (diisobutylphosphino)cyclopentadienenyl ligands. The two diisobutylphophine units are trans to each other with respect to the CoIII metal center. The PF6− anion links the cobaltocenium cations via weak C&...

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Main Authors: Man-Zhen Qiu, Ding-Biao Li, Jian-Guo Hou
Format: Article
Language:English
Published: International Union of Crystallography 2008-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808017194
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spelling doaj-3b690cc6189944d19fd105a318853cd22020-11-25T01:27:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-07-01647m927m92710.1107/S16005368080171941,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphateMan-Zhen QiuDing-Biao LiJian-Guo HouIn the title compound, [Co(C13H22P)2]PF6, the CoIII atom is sandwiched between two (diisobutylphosphino)cyclopentadienenyl ligands. The two diisobutylphophine units are trans to each other with respect to the CoIII metal center. The PF6− anion links the cobaltocenium cations via weak C—H...F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H...F hydrogen bonds, forming a layer extending parallel to the (10overline{1}) plane.http://scripts.iucr.org/cgi-bin/paper?S1600536808017194
collection DOAJ
language English
format Article
sources DOAJ
author Man-Zhen Qiu
Ding-Biao Li
Jian-Guo Hou
spellingShingle Man-Zhen Qiu
Ding-Biao Li
Jian-Guo Hou
1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
Acta Crystallographica Section E
author_facet Man-Zhen Qiu
Ding-Biao Li
Jian-Guo Hou
author_sort Man-Zhen Qiu
title 1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
title_short 1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
title_full 1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
title_fullStr 1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
title_full_unstemmed 1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
title_sort 1,1′-bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-07-01
description In the title compound, [Co(C13H22P)2]PF6, the CoIII atom is sandwiched between two (diisobutylphosphino)cyclopentadienenyl ligands. The two diisobutylphophine units are trans to each other with respect to the CoIII metal center. The PF6− anion links the cobaltocenium cations via weak C—H...F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H...F hydrogen bonds, forming a layer extending parallel to the (10overline{1}) plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808017194
work_keys_str_mv AT manzhenqiu 118242bisdiisobutylphosphinocobaltoceniumhexafluoridophosphate
AT dingbiaoli 118242bisdiisobutylphosphinocobaltoceniumhexafluoridophosphate
AT jianguohou 118242bisdiisobutylphosphinocobaltoceniumhexafluoridophosphate
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