The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate
Complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2·nH2O (M = Zn(II), Cd(II), n = 2, or M = Pt(II), Pd(II), n = 0), have been prepared and characterized by elemental an...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Serbian Chemical Society
2004-02-01
|
Series: | Journal of the Serbian Chemical Society |
Subjects: | |
Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol69/No2/V69-No2-06.pdf |
id |
doaj-3b74caa67c834f23ada63f8997e5c26d |
---|---|
record_format |
Article |
spelling |
doaj-3b74caa67c834f23ada63f8997e5c26d2020-11-24T20:54:20ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51392004-02-01692137143The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoateSRECKO TRIFUNOVICSVETLANA LUKICSONJA SKUBANZIVOSLAV TESICSLOBODAN A. GRUJICZORICA LEKAComplexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2·nH2O (M = Zn(II), Cd(II), n = 2, or M = Pt(II), Pd(II), n = 0), have been prepared and characterized by elemental analysis, IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode.http://www.shd.org.yu/HtDocs/SHD/Vol69/No2/V69-No2-06.pdfzinc(II)cadmium(II)platinum(II)palladium(II)complexessynthesisdithiocarbamate |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
SRECKO TRIFUNOVIC SVETLANA LUKIC SONJA SKUBAN ZIVOSLAV TESIC SLOBODAN A. GRUJIC ZORICA LEKA |
spellingShingle |
SRECKO TRIFUNOVIC SVETLANA LUKIC SONJA SKUBAN ZIVOSLAV TESIC SLOBODAN A. GRUJIC ZORICA LEKA The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate Journal of the Serbian Chemical Society zinc(II) cadmium(II) platinum(II) palladium(II) complexes synthesis dithiocarbamate |
author_facet |
SRECKO TRIFUNOVIC SVETLANA LUKIC SONJA SKUBAN ZIVOSLAV TESIC SLOBODAN A. GRUJIC ZORICA LEKA |
author_sort |
SRECKO TRIFUNOVIC |
title |
The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
title_short |
The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
title_full |
The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
title_fullStr |
The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
title_full_unstemmed |
The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
title_sort |
synthesis and characterization of complexes of zinc(ii), cadmium(ii), platinum(ii) and palladium(ii) with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate |
publisher |
Serbian Chemical Society |
series |
Journal of the Serbian Chemical Society |
issn |
0352-5139 |
publishDate |
2004-02-01 |
description |
Complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2·nH2O (M = Zn(II), Cd(II), n = 2, or M = Pt(II), Pd(II), n = 0), have been prepared and characterized by elemental analysis, IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode. |
topic |
zinc(II) cadmium(II) platinum(II) palladium(II) complexes synthesis dithiocarbamate |
url |
http://www.shd.org.yu/HtDocs/SHD/Vol69/No2/V69-No2-06.pdf |
work_keys_str_mv |
AT sreckotrifunovic thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT svetlanalukic thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT sonjaskuban thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT zivoslavtesic thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT slobodanagrujic thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT zoricaleka thesynthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT sreckotrifunovic synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT svetlanalukic synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT sonjaskuban synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT zivoslavtesic synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT slobodanagrujic synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate AT zoricaleka synthesisandcharacterizationofcomplexesofzinciicadmiumiiplatinumiiandpalladiumiiwithpotassium3dithiocarboxy3aza5aminopentanoate |
_version_ |
1716794813610721280 |