Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles
Aminohydrazide cross-linked chitosan (CLCS) and its MWCNTs (CLCS/MWCNTs) were formulated and utilized as a potent ecofriendly basic heterogeneous biocatalyst under ultrasonic irradiation for synthesis of two novel series of benzil bis-aryldiazenylthiazoles and benzil bis-arylhydrazonothiazolones fro...
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doaj-3ca10cc9ee1944efaa713df731dce7f52021-06-01T01:04:48ZengMDPI AGPolymers2073-43602021-05-01131728172810.3390/polym13111728Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-ThiazolesLatifah A. Alshabanah0Sobhi M. Gomha1Laila A. Al-Mutabagani2Tariq Z. Abolibda3Nahed A. Abd El-Ghany4Waleed A. M. A. El-Enany5Ahmed K. El-Ziaty6Rania S. Ali7Nadia A. Mohamed8Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, Riyadh 11671, Saudi ArabiaDepartment of Chemistry, Faculty of Science, Cairo University, Giza 12613, EgyptDepartment of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, Riyadh 11671, Saudi ArabiaDepartment of Chemistry, Faculty of Science, Islamic University in Almadinah Almonawara, Almadinah Almonawara 42351, Saudi ArabiaDepartment of Chemistry, Faculty of Science, Cairo University, Giza 12613, EgyptDepartment of Chemistry, Faculty of Science, Cairo University, Giza 12613, EgyptChemistry Department, Faculty of Science, Ain Shams University, El-Khalifa El-Mamoun, Abbassia, Cairo 11566, EgyptDepartment of Basic Science, Faculty of Technology and Education, Helwan University, Cairo 11795, EgyptDepartment of Chemistry, Faculty of Science, Cairo University, Giza 12613, EgyptAminohydrazide cross-linked chitosan (CLCS) and its MWCNTs (CLCS/MWCNTs) were formulated and utilized as a potent ecofriendly basic heterogeneous biocatalyst under ultrasonic irradiation for synthesis of two novel series of benzil bis-aryldiazenylthiazoles and benzil bis-arylhydrazonothiazolones from the reaction of benzil bis-thiosemicarbazone with 2-oxo-<i>N</i>′-arylpropanehydrazonoyl chlorides and ethyl 2-chloro-2-(2-phenylhydrazono) acetates, respectively. The chemical structures of the newly synthesized derivatives were elucidated by spectral data and alternative methods, where available. Additionally, their yield % was estimated using a traditional catalyst as TEA and green recyclable catalysts as CLCS and CLCS/MWCNTs composite in a comparative study. We observed that, under the same reaction conditions, the yield % of the desired products increased by changing TEA to CLCS then to CLCS/MWCNT from 72–78% to 79–83% to 84–87%, respectively. The thermal stability of the investigated samples could be arranged as CLCS/MWCNTs composite > CLCS > chitosan, where the weight losses of chitosan, CLCS and CLCS/MWCNTs composite at 500 °C were 65.46%, 57.95% and 53.29%, respectively.https://www.mdpi.com/2073-4360/13/11/1728thiosemicarazoneshydrazonoyl halidesbis-thiazolescross-linked chitosanmultiwalled carbon nanotubes/cross-linked chitosan composite |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Latifah A. Alshabanah Sobhi M. Gomha Laila A. Al-Mutabagani Tariq Z. Abolibda Nahed A. Abd El-Ghany Waleed A. M. A. El-Enany Ahmed K. El-Ziaty Rania S. Ali Nadia A. Mohamed |
spellingShingle |
Latifah A. Alshabanah Sobhi M. Gomha Laila A. Al-Mutabagani Tariq Z. Abolibda Nahed A. Abd El-Ghany Waleed A. M. A. El-Enany Ahmed K. El-Ziaty Rania S. Ali Nadia A. Mohamed Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles Polymers thiosemicarazones hydrazonoyl halides bis-thiazoles cross-linked chitosan multiwalled carbon nanotubes/cross-linked chitosan composite |
author_facet |
Latifah A. Alshabanah Sobhi M. Gomha Laila A. Al-Mutabagani Tariq Z. Abolibda Nahed A. Abd El-Ghany Waleed A. M. A. El-Enany Ahmed K. El-Ziaty Rania S. Ali Nadia A. Mohamed |
author_sort |
Latifah A. Alshabanah |
title |
Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles |
title_short |
Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles |
title_full |
Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles |
title_fullStr |
Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles |
title_full_unstemmed |
Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles |
title_sort |
cross-linked chitosan/multi-walled carbon nanotubes composite as ecofriendly biocatalyst for synthesis of some novel benzil bis-thiazoles |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2021-05-01 |
description |
Aminohydrazide cross-linked chitosan (CLCS) and its MWCNTs (CLCS/MWCNTs) were formulated and utilized as a potent ecofriendly basic heterogeneous biocatalyst under ultrasonic irradiation for synthesis of two novel series of benzil bis-aryldiazenylthiazoles and benzil bis-arylhydrazonothiazolones from the reaction of benzil bis-thiosemicarbazone with 2-oxo-<i>N</i>′-arylpropanehydrazonoyl chlorides and ethyl 2-chloro-2-(2-phenylhydrazono) acetates, respectively. The chemical structures of the newly synthesized derivatives were elucidated by spectral data and alternative methods, where available. Additionally, their yield % was estimated using a traditional catalyst as TEA and green recyclable catalysts as CLCS and CLCS/MWCNTs composite in a comparative study. We observed that, under the same reaction conditions, the yield % of the desired products increased by changing TEA to CLCS then to CLCS/MWCNT from 72–78% to 79–83% to 84–87%, respectively. The thermal stability of the investigated samples could be arranged as CLCS/MWCNTs composite > CLCS > chitosan, where the weight losses of chitosan, CLCS and CLCS/MWCNTs composite at 500 °C were 65.46%, 57.95% and 53.29%, respectively. |
topic |
thiosemicarazones hydrazonoyl halides bis-thiazoles cross-linked chitosan multiwalled carbon nanotubes/cross-linked chitosan composite |
url |
https://www.mdpi.com/2073-4360/13/11/1728 |
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