A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules

A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules

The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere...

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Main Authors: Wei Lu, Dinh Cao Huan Do, Rei Kinjo
Format: Article
Language:English
Published: Nature Publishing Group 2020-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-17166-9
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spelling doaj-3d2dad4fdf8d47a2a30e33b48da288b12021-07-11T11:45:09ZengNature Publishing GroupNature Communications2041-17232020-07-011111710.1038/s41467-020-17166-9A flat carborane with multiple aromaticity beyond Wade–Mingos’ rulesWei Lu0Dinh Cao Huan Do1Rei Kinjo2Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityThe polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT.https://doi.org/10.1038/s41467-020-17166-9
collection DOAJ
language English
format Article
sources DOAJ
author Wei Lu
Dinh Cao Huan Do
Rei Kinjo
spellingShingle Wei Lu
Dinh Cao Huan Do
Rei Kinjo
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
Nature Communications
author_facet Wei Lu
Dinh Cao Huan Do
Rei Kinjo
author_sort Wei Lu
title A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_short A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_full A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_fullStr A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_full_unstemmed A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
title_sort flat carborane with multiple aromaticity beyond wade–mingos’ rules
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-07-01
description The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT.
url https://doi.org/10.1038/s41467-020-17166-9
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