A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules
The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere...
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2020-07-01
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Online Access: | https://doi.org/10.1038/s41467-020-17166-9 |
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doaj-3d2dad4fdf8d47a2a30e33b48da288b12021-07-11T11:45:09ZengNature Publishing GroupNature Communications2041-17232020-07-011111710.1038/s41467-020-17166-9A flat carborane with multiple aromaticity beyond Wade–Mingos’ rulesWei Lu0Dinh Cao Huan Do1Rei Kinjo2Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityThe polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT.https://doi.org/10.1038/s41467-020-17166-9 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Wei Lu Dinh Cao Huan Do Rei Kinjo |
spellingShingle |
Wei Lu Dinh Cao Huan Do Rei Kinjo A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules Nature Communications |
author_facet |
Wei Lu Dinh Cao Huan Do Rei Kinjo |
author_sort |
Wei Lu |
title |
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules |
title_short |
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules |
title_full |
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules |
title_fullStr |
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules |
title_full_unstemmed |
A flat carborane with multiple aromaticity beyond Wade–Mingos’ rules |
title_sort |
flat carborane with multiple aromaticity beyond wade–mingos’ rules |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2020-07-01 |
description |
The polyhedral skeletal electron pair theory (PESPT), also known as Wade-Mingos’ rules, defines a relationship between skeletal bonding electron pairs and structure of clusters. Here the authors report the synthesis, structure and computational studies of planar C2B4R4 carboranes that do not adhere to PESPT. |
url |
https://doi.org/10.1038/s41467-020-17166-9 |
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