Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
In the salt, (NH4)2[Co(CH4O6P2)2(H2O)2], the methylenediphosphonate acts as a bidentate ligand and the CoII ion (site symmetry overline 1) assumes an octahedral CoO6 coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is f...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809042159 |
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doaj-3d329429de00452abb4c121416b1623c2020-11-25T01:39:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1394m139410.1107/S1600536809042159Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)K. A. Van der MerweHendrik G. VisserJ. A. VenterIn the salt, (NH4)2[Co(CH4O6P2)2(H2O)2], the methylenediphosphonate acts as a bidentate ligand and the CoII ion (site symmetry overline 1) assumes an octahedral CoO6 coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is formed through O—H...O and N—H...O hydrogen bonds between the cations and anions. http://scripts.iucr.org/cgi-bin/paper?S1600536809042159 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
K. A. Van der Merwe Hendrik G. Visser J. A. Venter |
| spellingShingle |
K. A. Van der Merwe Hendrik G. Visser J. A. Venter Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) Acta Crystallographica Section E |
| author_facet |
K. A. Van der Merwe Hendrik G. Visser J. A. Venter |
| author_sort |
K. A. Van der Merwe |
| title |
Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
| title_short |
Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
| title_full |
Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
| title_fullStr |
Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
| title_full_unstemmed |
Diammonium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
| title_sort |
diammonium diaquabis(methylenediphosphonato-κ2o,o′)cobaltate(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-11-01 |
| description |
In the salt, (NH4)2[Co(CH4O6P2)2(H2O)2], the methylenediphosphonate acts as a bidentate ligand and the CoII ion (site symmetry overline 1) assumes an octahedral CoO6 coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is formed through O—H...O and N—H...O hydrogen bonds between the cations and anions. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809042159 |
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