Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium

Sulfur is abundant in the Universe, but the observed abundance ratio of SH to H2S doesn’t agree with astrochemical models. The authors measure product state-resolved translational energy spectra of photoproducts in a jet-cooled H2S beam as a function of wavelength, showing that SH yield is lower tha...

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Main Authors:	Jiami Zhou, Yarui Zhao, Christopher S. Hansen, Jiayue Yang, Yao Chang, Yong Yu, Gongkui Cheng, Zhichao Chen, Zhigang He, Shengrui Yu, Hongbin Ding, Weiqing Zhang, Guorong Wu, Dongxu Dai, Colin M. Western, Michael N. R. Ashfold, Kaijun Yuan, Xueming Yang
Format:	Article
Language:	English
Published:	Nature Publishing Group 2020-03-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-020-15343-4

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spelling	doaj-3d3d049e5549412eb63ee6332d1ad8842021-05-11T08:37:48ZengNature Publishing GroupNature Communications2041-17232020-03-011111810.1038/s41467-020-15343-4Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar mediumJiami Zhou0Yarui Zhao1Christopher S. Hansen2Jiayue Yang3Yao Chang4Yong Yu5Gongkui Cheng6Zhichao Chen7Zhigang He8Shengrui Yu9Hongbin Ding10Weiqing Zhang11Guorong Wu12Dongxu Dai13Colin M. Western14Michael N. R. Ashfold15Kaijun Yuan16Xueming Yang17State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesSchool of Chemistry, University of New South WalesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesHangzhou Institute of Advanced Studies, Zhejiang Normal UniversitySchool of Physics, Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, Dalian University of TechnologyState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesSchool of Chemistry, University of BristolSchool of Chemistry, University of BristolState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesSulfur is abundant in the Universe, but the observed abundance ratio of SH to H2S doesn’t agree with astrochemical models. The authors measure product state-resolved translational energy spectra of photoproducts in a jet-cooled H2S beam as a function of wavelength, showing that SH yield is lower than assumed in the models.https://doi.org/10.1038/s41467-020-15343-4
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jiami Zhou Yarui Zhao Christopher S. Hansen Jiayue Yang Yao Chang Yong Yu Gongkui Cheng Zhichao Chen Zhigang He Shengrui Yu Hongbin Ding Weiqing Zhang Guorong Wu Dongxu Dai Colin M. Western Michael N. R. Ashfold Kaijun Yuan Xueming Yang
spellingShingle	Jiami Zhou Yarui Zhao Christopher S. Hansen Jiayue Yang Yao Chang Yong Yu Gongkui Cheng Zhichao Chen Zhigang He Shengrui Yu Hongbin Ding Weiqing Zhang Guorong Wu Dongxu Dai Colin M. Western Michael N. R. Ashfold Kaijun Yuan Xueming Yang Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium Nature Communications
author_facet	Jiami Zhou Yarui Zhao Christopher S. Hansen Jiayue Yang Yao Chang Yong Yu Gongkui Cheng Zhichao Chen Zhigang He Shengrui Yu Hongbin Ding Weiqing Zhang Guorong Wu Dongxu Dai Colin M. Western Michael N. R. Ashfold Kaijun Yuan Xueming Yang
author_sort	Jiami Zhou
title	Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium
title_short	Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium
title_full	Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium
title_fullStr	Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium
title_full_unstemmed	Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium
title_sort	ultraviolet photolysis of h2s and its implications for sh radical production in the interstellar medium
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2020-03-01
description	Sulfur is abundant in the Universe, but the observed abundance ratio of SH to H2S doesn’t agree with astrochemical models. The authors measure product state-resolved translational energy spectra of photoproducts in a jet-cooled H2S beam as a function of wavelength, showing that SH yield is lower than assumed in the models.
url	https://doi.org/10.1038/s41467-020-15343-4
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Ultraviolet photolysis of H2S and its implications for SH radical production in the interstellar medium

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