[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)

[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)

In the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine l...

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Main Authors: Aliakbar Dehno Khalaji, Bahram Bahramian, Khadijeh Jafari, Karla Fejfarová, Michal Dušek
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681202884X
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spelling doaj-3d4d19c80d1848599767151e878630c22020-11-25T01:33:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m1001m100210.1107/S160053681202884X[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)Aliakbar Dehno KhalajiBahram BahramianKhadijeh JafariKarla FejfarováMichal DušekIn the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S160053681202884X
collection DOAJ
language English
format Article
sources DOAJ
author Aliakbar Dehno Khalaji
Bahram Bahramian
Khadijeh Jafari
Karla Fejfarová
Michal Dušek
spellingShingle Aliakbar Dehno Khalaji
Bahram Bahramian
Khadijeh Jafari
Karla Fejfarová
Michal Dušek
[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
Acta Crystallographica Section E
author_facet Aliakbar Dehno Khalaji
Bahram Bahramian
Khadijeh Jafari
Karla Fejfarová
Michal Dušek
author_sort Aliakbar Dehno Khalaji
title [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
title_short [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
title_full [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
title_fullStr [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
title_full_unstemmed [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
title_sort [4-bromo-n-(pyridin-2-ylmethylidene)aniline-κ2n,n′]iodido(triphenylphosphane-κp)copper(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description In the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å].
url http://scripts.iucr.org/cgi-bin/paper?S160053681202884X
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AT bahrambahramian 4bromonpyridin2ylmethylideneanilineamp9542nnamp8242iodidotriphenylphosphaneamp954pcopperi
AT khadijehjafari 4bromonpyridin2ylmethylideneanilineamp9542nnamp8242iodidotriphenylphosphaneamp954pcopperi
AT karlafejfarovamp225 4bromonpyridin2ylmethylideneanilineamp9542nnamp8242iodidotriphenylphosphaneamp954pcopperi
AT michalduamp353ek 4bromonpyridin2ylmethylideneanilineamp9542nnamp8242iodidotriphenylphosphaneamp954pcopperi
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