2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2)
The asymmetric unit of the title compound, C6H5Cl2N·2C11H11Cl2NO, is composed of one molecule of an enamino–ketone [i.e. –(2,6-dichlorophenylamino)pent-3-en-2-one] and half a molecule of 2,6-dichloroaniline, the whole molecule of the latter component being generated by t...
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International Union of Crystallography
2013-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812049227 |
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doaj-3ea0b1f42d9144d7a5cd6b1d6ac938a42020-11-25T01:56:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-01-01691o34o3510.1107/S16005368120492272,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2)Gertruida J. S. VenterGideon SteylAndreas RoodtThe asymmetric unit of the title compound, C6H5Cl2N·2C11H11Cl2NO, is composed of one molecule of an enamino–ketone [i.e. –(2,6-dichlorophenylamino)pent-3-en-2-one] and half a molecule of 2,6-dichloroaniline, the whole molecule of the latter component being generated by twofold rotational symmetry. In this latter molecule, there are two intramolecular N—H...Cl contacts. In the enamino–ketone molecule, there is an N—H...O hydrogen bond of moderate strength, and the dihedral angle between the benzene ring and pentanone fragment [C—C(—N)=C—C(=O)—C; planar within 0.005 (1) Å] is 81.85 (7)°. In the crystal, two molecules of the enamino–ketone are bridged by a molecule of 2,6-dichloroaniline via N—H...O hydrogen bonds of moderate strength. There are also π–π interactions present, involving the benzene rings of inversion-related enamino–ketone molecules [centroid–centroid distance = 3.724 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812049227 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Gertruida J. S. Venter Gideon Steyl Andreas Roodt |
spellingShingle |
Gertruida J. S. Venter Gideon Steyl Andreas Roodt 2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) Acta Crystallographica Section E |
author_facet |
Gertruida J. S. Venter Gideon Steyl Andreas Roodt |
author_sort |
Gertruida J. S. Venter |
title |
2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
title_short |
2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
title_full |
2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
title_fullStr |
2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
title_full_unstemmed |
2,6-Dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
title_sort |
2,6-dichloroaniline–4-(2,6-dichloroanilino)pent-3-en-2-one (1/2) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2013-01-01 |
description |
The asymmetric unit of the title compound, C6H5Cl2N·2C11H11Cl2NO, is composed of one molecule of an enamino–ketone [i.e. –(2,6-dichlorophenylamino)pent-3-en-2-one] and half a molecule of 2,6-dichloroaniline, the whole molecule of the latter component being generated by twofold rotational symmetry. In this latter molecule, there are two intramolecular N—H...Cl contacts. In the enamino–ketone molecule, there is an N—H...O hydrogen bond of moderate strength, and the dihedral angle between the benzene ring and pentanone fragment [C—C(—N)=C—C(=O)—C; planar within 0.005 (1) Å] is 81.85 (7)°. In the crystal, two molecules of the enamino–ketone are bridged by a molecule of 2,6-dichloroaniline via N—H...O hydrogen bonds of moderate strength. There are also π–π interactions present, involving the benzene rings of inversion-related enamino–ketone molecules [centroid–centroid distance = 3.724 (4) Å]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812049227 |
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