μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

The title compound, [Cu2(C7H3NO5)2(C10H8N2)(H2O)2], exhibits a centrosymmetric binuclear molecule. Each completely deprotonated 4-hydroxypyridine-2,6-dicarboxylic acid molecule assumes a tridentate chelating coordination mode. The square-pyramidal coordination geometry around the CuII ion is complet...

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Main Authors: Mei-Li Zhang, Hua-Li Cui, Lou-Jun Gao, Xiao-Li Chen, Ya-Li Qiao
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812004758
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spelling doaj-3f5da5a1db654f92b3396f99033a4ec92020-11-24T21:29:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m326m32710.1107/S1600536812004758μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]Mei-Li ZhangHua-Li CuiLou-Jun GaoXiao-Li ChenYa-Li QiaoThe title compound, [Cu2(C7H3NO5)2(C10H8N2)(H2O)2], exhibits a centrosymmetric binuclear molecule. Each completely deprotonated 4-hydroxypyridine-2,6-dicarboxylic acid molecule assumes a tridentate chelating coordination mode. The square-pyramidal coordination geometry around the CuII ion is completed by the bridging bipyridine ligand and an apical water molecule. Adjacent complexes are connected via O—H...O and C—H...O hydrogen bonds to generate a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812004758
collection DOAJ
language English
format Article
sources DOAJ
author Mei-Li Zhang
Hua-Li Cui
Lou-Jun Gao
Xiao-Li Chen
Ya-Li Qiao
spellingShingle Mei-Li Zhang
Hua-Li Cui
Lou-Jun Gao
Xiao-Li Chen
Ya-Li Qiao
μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
Acta Crystallographica Section E
author_facet Mei-Li Zhang
Hua-Li Cui
Lou-Jun Gao
Xiao-Li Chen
Ya-Li Qiao
author_sort Mei-Li Zhang
title μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
title_short μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
title_full μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
title_fullStr μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
title_full_unstemmed μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]
title_sort μ-4,4′-bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The title compound, [Cu2(C7H3NO5)2(C10H8N2)(H2O)2], exhibits a centrosymmetric binuclear molecule. Each completely deprotonated 4-hydroxypyridine-2,6-dicarboxylic acid molecule assumes a tridentate chelating coordination mode. The square-pyramidal coordination geometry around the CuII ion is completed by the bridging bipyridine ligand and an apical water molecule. Adjacent complexes are connected via O—H...O and C—H...O hydrogen bonds to generate a three-dimensional supramolecular structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812004758
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AT hualicui amp95644amp8242bipyridinebisaqua4hydroxypyridine26dicarboxylatocopperii
AT loujungao amp95644amp8242bipyridinebisaqua4hydroxypyridine26dicarboxylatocopperii
AT xiaolichen amp95644amp8242bipyridinebisaqua4hydroxypyridine26dicarboxylatocopperii
AT yaliqiao amp95644amp8242bipyridinebisaqua4hydroxypyridine26dicarboxylatocopperii
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