μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}

μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}

The title compound, [Fe4(C5H5OS)2S(CO)12], was prepared by the direct reaction of Fe3(CO)12 and 2-furylmethanethiol in tetrahydrofuran. Desulfurization took place readily to form an Fe4S3 cluster. The molecule consists of two similar [(μ-2-C4H3O—CH2S)Fe2(CO)6] moieties joi...

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Main Authors: Cong Han, Xiao-Nan Huang, Yan-Ling Guo, Wei Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810022634
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spelling doaj-3f9f833841754346a31a90ebc124cfbf2020-11-25T00:20:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m820m82010.1107/S1600536810022634μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}Cong HanXiao-Nan HuangYan-Ling GuoWei LiuThe title compound, [Fe4(C5H5OS)2S(CO)12], was prepared by the direct reaction of Fe3(CO)12 and 2-furylmethanethiol in tetrahydrofuran. Desulfurization took place readily to form an Fe4S3 cluster. The molecule consists of two similar [(μ-2-C4H3O—CH2S)Fe2(CO)6] moieties joined to a spiro-type four-coordinate μ4-S atom such that this bridging sulfur is tetrahedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furylmethanethiolate ligand bridges the two Fe atoms. http://scripts.iucr.org/cgi-bin/paper?S1600536810022634
collection DOAJ
language English
format Article
sources DOAJ
author Cong Han
Xiao-Nan Huang
Yan-Ling Guo
Wei Liu
spellingShingle Cong Han
Xiao-Nan Huang
Yan-Ling Guo
Wei Liu
μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
Acta Crystallographica Section E
author_facet Cong Han
Xiao-Nan Huang
Yan-Ling Guo
Wei Liu
author_sort Cong Han
title μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
title_short μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
title_full μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
title_fullStr μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
title_full_unstemmed μ4-Sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}
title_sort μ4-sulfido-bis{(μ-2-furylmethanethiolato)bis[tricarbonyliron](fe—fe)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description The title compound, [Fe4(C5H5OS)2S(CO)12], was prepared by the direct reaction of Fe3(CO)12 and 2-furylmethanethiol in tetrahydrofuran. Desulfurization took place readily to form an Fe4S3 cluster. The molecule consists of two similar [(μ-2-C4H3O—CH2S)Fe2(CO)6] moieties joined to a spiro-type four-coordinate μ4-S atom such that this bridging sulfur is tetrahedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furylmethanethiolate ligand bridges the two Fe atoms.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810022634
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AT xiaonanhuang amp9564sulfidobisamp9562furylmethanethiolatobistricarbonylironfeamp8212fe
AT yanlingguo amp9564sulfidobisamp9562furylmethanethiolatobistricarbonylironfeamp8212fe
AT weiliu amp9564sulfidobisamp9562furylmethanethiolatobistricarbonylironfeamp8212fe
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