catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]

catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]

The asymmetric unit of the title compound {(C6H18N2)2[Sb2Br10]·H2O}n, consists of two tetramethylethylendiammonium cations that are located on centres of inversion, as well as one tetramethylethylendiammonium cation, one water molecule, one distorted octahedral [SbBr6]3−anion and...

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Main Authors: François Michaud, Slaheddine Kamoun, Houda Kharrat
Format: Article
Language:English
Published: International Union of Crystallography 2013-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813028894
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spelling doaj-403db928f24741c395f0b6d0efcc3c312020-11-24T22:15:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m637m63810.1107/S1600536813028894catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]François MichaudSlaheddine KamounHouda KharratThe asymmetric unit of the title compound {(C6H18N2)2[Sb2Br10]·H2O}n, consists of two tetramethylethylendiammonium cations that are located on centres of inversion, as well as one tetramethylethylendiammonium cation, one water molecule, one distorted octahedral [SbBr6]3−anion and one bisphenoidal [SbBr4]− anion in general positions. The [SbBr6]3− and [SbBr4]− anions are linked together by two long Sb—Br bonds of 3.2709 (8) and 3.5447 (7) Å into {[Sb2Br10]4−}n chains along [001]. One of the three tetramethylethylendiammonium cations is disordered and was refined using a split model (occupancy ratio 0.58:0.42). The cations and the water molecule are connected to the {[Sb2Br10]4−}n polymeric anions by weak N—H ...Br and O(water)—H ...Br hydrogen bonding.http://scripts.iucr.org/cgi-bin/paper?S1600536813028894
collection DOAJ
language English
format Article
sources DOAJ
author François Michaud
Slaheddine Kamoun
Houda Kharrat
spellingShingle François Michaud
Slaheddine Kamoun
Houda Kharrat
catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
Acta Crystallographica Section E
author_facet François Michaud
Slaheddine Kamoun
Houda Kharrat
author_sort François Michaud
title catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
title_short catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
title_full catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
title_fullStr catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
title_full_unstemmed catena-Poly[N,N,N′,N′-tetramethylethylendiammonium [[tetrabromidoantimonate(III)]-μ-bromido] hemihydrate]
title_sort catena-poly[n,n,n′,n′-tetramethylethylendiammonium [[tetrabromidoantimonate(iii)]-μ-bromido] hemihydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-12-01
description The asymmetric unit of the title compound {(C6H18N2)2[Sb2Br10]·H2O}n, consists of two tetramethylethylendiammonium cations that are located on centres of inversion, as well as one tetramethylethylendiammonium cation, one water molecule, one distorted octahedral [SbBr6]3−anion and one bisphenoidal [SbBr4]− anion in general positions. The [SbBr6]3− and [SbBr4]− anions are linked together by two long Sb—Br bonds of 3.2709 (8) and 3.5447 (7) Å into {[Sb2Br10]4−}n chains along [001]. One of the three tetramethylethylendiammonium cations is disordered and was refined using a split model (occupancy ratio 0.58:0.42). The cations and the water molecule are connected to the {[Sb2Br10]4−}n polymeric anions by weak N—H ...Br and O(water)—H ...Br hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813028894
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AT slaheddinekamoun catenapolynnn8242n8242tetramethylethylendiammoniumtetrabromidoantimonateiii956bromidohemihydrate
AT houdakharrat catenapolynnn8242n8242tetramethylethylendiammoniumtetrabromidoantimonateiii956bromidohemihydrate
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