Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline
New complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z] and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis- I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.<br />phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) hav...
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| Format: | Article |
| Language: | Arabic |
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College of Education for Pure Sciences
2019-08-01
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| Series: | مجلة التربية والعلم |
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| Online Access: | https://edusj.mosuljournals.com/article_162869_f444b92d3974835ecb3244b43617e393.pdf |
| Summary: | New complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z] and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis- I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.<br />phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) have been prepared in basic medium. The complexes and adducts were ihaiacterized by atomic absorption, conductivity measurements,spectral (lR and electronic) and molecular weight measurements studies' ietrahedral environment around the metal ions in the complexes and<br />octahedral geometry in the adducts were suggested according to the above measurements. |
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| ISSN: | 1812-125X 2664-2530 |