Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline
New complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z] and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis- I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.<br />phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) hav...
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doaj-409a590e8adc4fccb5c261848698bd932020-11-25T00:26:17ZaraCollege of Education for Pure Sciencesمجلة التربية والعلم1812-125X2664-25302019-08-011911810.33899/edusj.2019.162869162869Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthrolineF. SaiedNew complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z] and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis- I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.<br />phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) have been prepared in basic medium. The complexes and adducts were ihaiacterized by atomic absorption, conductivity measurements,spectral (lR and electronic) and molecular weight measurements studies' ietrahedral environment around the metal ions in the complexes and<br />octahedral geometry in the adducts were suggested according to the above measurements.https://edusj.mosuljournals.com/article_162869_f444b92d3974835ecb3244b43617e393.pdfthioether ligandsphenanthrolineatomic absorption |
collection |
DOAJ |
language |
Arabic |
format |
Article |
sources |
DOAJ |
author |
F. Saied |
spellingShingle |
F. Saied Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline مجلة التربية والعلم thioether ligands phenanthroline atomic absorption |
author_facet |
F. Saied |
author_sort |
F. Saied |
title |
Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
title_short |
Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
title_full |
Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
title_fullStr |
Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
title_full_unstemmed |
Synthesis and characterization of zn(ll),cd(Il) and Hg(II) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
title_sort |
synthesis and characterization of zn(ll),cd(il) and hg(ii) complexes with thioether ligands and their adducts with 1,10 phenanthroline |
publisher |
College of Education for Pure Sciences |
series |
مجلة التربية والعلم |
issn |
1812-125X 2664-2530 |
publishDate |
2019-08-01 |
description |
New complexes of general formula [M(LXSBu'')2],[M(L)(SFur)z] and adducts [M(L)(SBu")2(phen)]. [M(L)(SFur)z(phen)l,where L:C is-bis- I .2-(phenylthio)ethylene. SBu'': 1 -butanethiol. SFur:2-furanmethanthiol.<br />phen:1,10 phenanthroline, M:Zn(ll).cd(ll) and FIg(ll) have been prepared in basic medium. The complexes and adducts were ihaiacterized by atomic absorption, conductivity measurements,spectral (lR and electronic) and molecular weight measurements studies' ietrahedral environment around the metal ions in the complexes and<br />octahedral geometry in the adducts were suggested according to the above measurements. |
topic |
thioether ligands phenanthroline atomic absorption |
url |
https://edusj.mosuljournals.com/article_162869_f444b92d3974835ecb3244b43617e393.pdf |
work_keys_str_mv |
AT fsaied synthesisandcharacterizationofznllcdilandhgiicomplexeswiththioetherligandsandtheiradductswith110phenanthroline |
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1725344995513204736 |