(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine
The title chiral ferrocene compound, [Fe(C5H5)(C18H25N2)], contains one planar and two central chiral centers. It is of interest with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH...
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International Union of Crystallography
2009-04-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809008861 |
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doaj-40ab8db273be437a83373516b6f60dc62020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m432m43210.1107/S1600536809008861(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamineXiu-Li ZhengJin-Ting LiuThe title chiral ferrocene compound, [Fe(C5H5)(C18H25N2)], contains one planar and two central chiral centers. It is of interest with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH carbon of the ethanamine unit and S at the CH carbon of the phenylethylamino substituent. In the ferrocenyl unit, the cyclopentadienyl (Cp) rings are planar, with maximum deviations of 0.002 (2) Å for the substituted and 0.008 (3) Å for the unsubstituted Cp ring. The dihedral angle between the ring planes is 2.12 (15)° and the rings are twisted slightly from an eclipsed conformation by 7.06–7.60°. http://scripts.iucr.org/cgi-bin/paper?S1600536809008861 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xiu-Li Zheng Jin-Ting Liu |
spellingShingle |
Xiu-Li Zheng Jin-Ting Liu (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine Acta Crystallographica Section E |
author_facet |
Xiu-Li Zheng Jin-Ting Liu |
author_sort |
Xiu-Li Zheng |
title |
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
title_short |
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
title_full |
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
title_fullStr |
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
title_full_unstemmed |
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
title_sort |
(s,r,rp)-n,n-dimethyl-1-{2-[(1-phenylethyl)aminomethyl]ferrocenyl}ethanamine |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-04-01 |
description |
The title chiral ferrocene compound, [Fe(C5H5)(C18H25N2)], contains one planar and two central chiral centers. It is of interest with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH carbon of the ethanamine unit and S at the CH carbon of the phenylethylamino substituent. In the ferrocenyl unit, the cyclopentadienyl (Cp) rings are planar, with maximum deviations of 0.002 (2) Å for the substituted and 0.008 (3) Å for the unsubstituted Cp ring. The dihedral angle between the ring planes is 2.12 (15)° and the rings are twisted slightly from an eclipsed conformation by 7.06–7.60°. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809008861 |
work_keys_str_mv |
AT xiulizheng srrpnndimethyl121phenylethylaminomethylferrocenylethanamine AT jintingliu srrpnndimethyl121phenylethylaminomethylferrocenylethanamine |
_version_ |
1724900234361831424 |