(Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate
In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as t...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2018-01-01
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Series: | IUCrData |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314618000378 |
Summary: | In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as the apices of a trigonal bipyramid [Cu—B = 2.0456 (16) Å and Cu—O = 1.9957 (11) Å]. The amide group of the latter ligand is involved in a bifurcated hydrogen bond to the trifluoromethanesulfonate anion. |
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ISSN: | 2414-3146 |