(Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate

(Acetamide-κO){2,2′,2′′-boranetriyltris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ4B,S,S′,S′′}copper(I) trifluoromethanesulfonate chloroform disolvate

In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as t...

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Bibliographic Details
Main Authors: Stefan Holler, Ferdinand Belaj, Nadia C. Mösch-Zanetti
Format: Article
Language:English
Published: International Union of Crystallography 2018-01-01
Series:IUCrData
Subjects:
crystal structure
copper
trigonal–bipyramidal coordination
scorpionate
boratrane
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314618000378
Description
Summary:In the title solvated complex salt, [Cu(C27H39BN6S3)(C2H5NO)](CF3O3S)·2CHCl3, the CuI atom is coordinated by the three S atoms of the pyridazine-3-thione rings in the equatorial plane [Cu—S = 2.3072 (4)–2.3280 (4) Å] and the B atom of the scorpionate ligand and the O atom of an acetamide ligand as the apices of a trigonal bipyramid [Cu—B = 2.0456 (16) Å and Cu—O = 1.9957 (11) Å]. The amide group of the latter ligand is involved in a bifurcated hydrogen bond to the trifluoromethanesulfonate anion.
ISSN:2414-3146

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