In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule

New approaches are required to access metal-organic assemblies with unusual structural properties. Here, the authors use an in situ redox reaction to obtain a mixed-valence, Mn(II)/Mn(III)-containing metal-organic nanocapsule with an odd number of metal ions.

Bibliographic Details
Main Authors:	Asanka S. Rathnayake, Hector W. L. Fraser, Euan K. Brechin, Scott J. Dalgarno, Jakob E. Baumeister, Joshua White, Pokpong Rungthanaphatsophon, Justin R. Walensky, Charles L. Barnes, Simon J. Teat, Jerry L. Atwood
Format:	Article
Language:	English
Published:	Nature Publishing Group 2018-05-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-04541-w

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spelling	doaj-415c36e3c1664396953d80934f3dae4f2021-05-11T10:10:54ZengNature Publishing GroupNature Communications2041-17232018-05-01911610.1038/s41467-018-04541-wIn situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsuleAsanka S. Rathnayake0Hector W. L. Fraser1Euan K. Brechin2Scott J. Dalgarno3Jakob E. Baumeister4Joshua White5Pokpong Rungthanaphatsophon6Justin R. Walensky7Charles L. Barnes8Simon J. Teat9Jerry L. Atwood10Department of Chemistry, University of MissouriEaStCHEM School of Chemistry, The University of EdinburghEaStCHEM School of Chemistry, The University of EdinburghInstitute of Chemical Sciences, Heriot-Watt University, RiccartonDepartment of Chemistry, University of MissouriDepartment of Chemistry, University of MissouriDepartment of Chemistry, University of MissouriDepartment of Chemistry, University of MissouriDepartment of Chemistry, University of MissouriAdvanced Light Source, Lawrence Berkeley National LaboratoryDepartment of Chemistry, University of MissouriNew approaches are required to access metal-organic assemblies with unusual structural properties. Here, the authors use an in situ redox reaction to obtain a mixed-valence, Mn(II)/Mn(III)-containing metal-organic nanocapsule with an odd number of metal ions.https://doi.org/10.1038/s41467-018-04541-w
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Asanka S. Rathnayake Hector W. L. Fraser Euan K. Brechin Scott J. Dalgarno Jakob E. Baumeister Joshua White Pokpong Rungthanaphatsophon Justin R. Walensky Charles L. Barnes Simon J. Teat Jerry L. Atwood
spellingShingle	Asanka S. Rathnayake Hector W. L. Fraser Euan K. Brechin Scott J. Dalgarno Jakob E. Baumeister Joshua White Pokpong Rungthanaphatsophon Justin R. Walensky Charles L. Barnes Simon J. Teat Jerry L. Atwood In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule Nature Communications
author_facet	Asanka S. Rathnayake Hector W. L. Fraser Euan K. Brechin Scott J. Dalgarno Jakob E. Baumeister Joshua White Pokpong Rungthanaphatsophon Justin R. Walensky Charles L. Barnes Simon J. Teat Jerry L. Atwood
author_sort	Asanka S. Rathnayake
title	In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
title_short	In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
title_full	In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
title_fullStr	In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
title_full_unstemmed	In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
title_sort	in situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2018-05-01
description	New approaches are required to access metal-organic assemblies with unusual structural properties. Here, the authors use an in situ redox reaction to obtain a mixed-valence, Mn(II)/Mn(III)-containing metal-organic nanocapsule with an odd number of metal ions.
url	https://doi.org/10.1038/s41467-018-04541-w
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In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule

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