In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
New approaches are required to access metal-organic assemblies with unusual structural properties. Here, the authors use an in situ redox reaction to obtain a mixed-valence, Mn(II)/Mn(III)-containing metal-organic nanocapsule with an odd number of metal ions.
Main Authors: | Asanka S. Rathnayake, Hector W. L. Fraser, Euan K. Brechin, Scott J. Dalgarno, Jakob E. Baumeister, Joshua White, Pokpong Rungthanaphatsophon, Justin R. Walensky, Charles L. Barnes, Simon J. Teat, Jerry L. Atwood |
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Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2018-05-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-018-04541-w |
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