Synthesis and Characterization of New Cyclic Aminobenzoquinones
The aim of this research is to synthesize and characterize of new cyclic members of cyclic aminobenzoquinones. Mono amino substituted products; 2-chloro-5,6-dimethyl-3-(pyrrolidin-1-yl)-1,4-benzoquinone (2), 2-chloro-5,6-dimethyl-3-(piperidin-1-yl)-1,4-benzoquinone (3), 2-chloro-5,6-dimethyl-3-m...
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doaj-41707c499e804465a1edfb6184df47292020-11-24T21:45:05ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202149-01202018-01-015237138010.18596/jotcsa.348606Synthesis and Characterization of New Cyclic AminobenzoquinonesAmaç Fatih TuyunMahmut Yıldız The aim of this research is to synthesize and characterize of new cyclic members of cyclic aminobenzoquinones. Mono amino substituted products; 2-chloro-5,6-dimethyl-3-(pyrrolidin-1-yl)-1,4-benzoquinone (2), 2-chloro-5,6-dimethyl-3-(piperidin-1-yl)-1,4-benzoquinone (3), 2-chloro-5,6-dimethyl-3-morpholino-1,4-benzoquinone (4), and 2-chloro-5,6-dimethyl-3-thiomorpholino-1,4-benzoquinone (5) have been synthesized by a green methodology using water as solvent by means of nucleophilic substitution reactions between 2,3-dichloro-5,6-dimethyl-1,4-benzoquinone (1) and cyclic secondary amines. Structure determination of the new products (2-5) was established on the basis of IR, 1H NMR, 13C NMR, and mass spectrometry. http://dergipark.gov.tr/jotcsa/issue/33408/348606Benzoquinonessecondary amineaminoquinones |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Amaç Fatih Tuyun Mahmut Yıldız |
spellingShingle |
Amaç Fatih Tuyun Mahmut Yıldız Synthesis and Characterization of New Cyclic Aminobenzoquinones Journal of the Turkish Chemical Society, Section A: Chemistry Benzoquinones secondary amine aminoquinones |
author_facet |
Amaç Fatih Tuyun Mahmut Yıldız |
author_sort |
Amaç Fatih Tuyun |
title |
Synthesis and Characterization of New Cyclic Aminobenzoquinones |
title_short |
Synthesis and Characterization of New Cyclic Aminobenzoquinones |
title_full |
Synthesis and Characterization of New Cyclic Aminobenzoquinones |
title_fullStr |
Synthesis and Characterization of New Cyclic Aminobenzoquinones |
title_full_unstemmed |
Synthesis and Characterization of New Cyclic Aminobenzoquinones |
title_sort |
synthesis and characterization of new cyclic aminobenzoquinones |
publisher |
Turkish Chemical Society |
series |
Journal of the Turkish Chemical Society, Section A: Chemistry |
issn |
2149-0120 2149-0120 |
publishDate |
2018-01-01 |
description |
The aim of this research is to synthesize and characterize of new cyclic members of cyclic aminobenzoquinones. Mono amino substituted products; 2-chloro-5,6-dimethyl-3-(pyrrolidin-1-yl)-1,4-benzoquinone (2), 2-chloro-5,6-dimethyl-3-(piperidin-1-yl)-1,4-benzoquinone (3), 2-chloro-5,6-dimethyl-3-morpholino-1,4-benzoquinone (4), and 2-chloro-5,6-dimethyl-3-thiomorpholino-1,4-benzoquinone (5) have been synthesized by a green methodology using water as solvent by means of nucleophilic substitution reactions between 2,3-dichloro-5,6-dimethyl-1,4-benzoquinone (1) and cyclic secondary amines. Structure determination of the new products (2-5) was established on the basis of IR, 1H NMR, 13C NMR, and mass spectrometry.
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topic |
Benzoquinones secondary amine aminoquinones |
url |
http://dergipark.gov.tr/jotcsa/issue/33408/348606 |
work_keys_str_mv |
AT amacfatihtuyun synthesisandcharacterizationofnewcyclicaminobenzoquinones AT mahmutyıldız synthesisandcharacterizationofnewcyclicaminobenzoquinones |
_version_ |
1725906820499767296 |