(1-Naphthyliminomethyl)ferrocene
In the title molecule, [Fe(C5H5)(C16H12N)], the cyclopentadienyl rings are approximately eclipsed and the interplanar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclopentadienyl ring, with an Fe...centroid distance of 1.639 (2) ...
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International Union of Crystallography
2008-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808026330 |
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doaj-42d9a405bae64bc09ee10999626ba1012020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1183m118310.1107/S1600536808026330(1-Naphthyliminomethyl)ferroceneYunbo ZangIn the title molecule, [Fe(C5H5)(C16H12N)], the cyclopentadienyl rings are approximately eclipsed and the interplanar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclopentadienyl ring, with an Fe...centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclopentadienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthalene ring system is 47.1 (1)°. The C—N=C—C torsion angle is 177.32 (5)°.http://scripts.iucr.org/cgi-bin/paper?S1600536808026330 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Yunbo Zang |
spellingShingle |
Yunbo Zang (1-Naphthyliminomethyl)ferrocene Acta Crystallographica Section E |
author_facet |
Yunbo Zang |
author_sort |
Yunbo Zang |
title |
(1-Naphthyliminomethyl)ferrocene |
title_short |
(1-Naphthyliminomethyl)ferrocene |
title_full |
(1-Naphthyliminomethyl)ferrocene |
title_fullStr |
(1-Naphthyliminomethyl)ferrocene |
title_full_unstemmed |
(1-Naphthyliminomethyl)ferrocene |
title_sort |
(1-naphthyliminomethyl)ferrocene |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-09-01 |
description |
In the title molecule, [Fe(C5H5)(C16H12N)], the cyclopentadienyl rings are approximately eclipsed and the interplanar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclopentadienyl ring, with an Fe...centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclopentadienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthalene ring system is 47.1 (1)°. The C—N=C—C torsion angle is 177.32 (5)°. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808026330 |
work_keys_str_mv |
AT yunbozang 1naphthyliminomethylferrocene |
_version_ |
1725378970658013184 |