{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoeuropium(III)zinc(II)

• Main Authors: Rong-Hua Hu, Li Chen, Yan Sui, Chun-Mei He
• Format: Article
• Language: English
• Published: International Union of Crystallography 2008-01-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S160053680706151X

In the title heteronuclear ZnII–EuIII complex [systematic name: {6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ4O1,O1′,O6,O6′:2κ4O1,N,N′,O1′}-μ-nitrato-1:2κ2O:O′-dinitrato-1κ4O,O′-europium(III)zinc(II)], [EuZn(C18H18N2O4)(NO3)3], with the hexadentate Schiff base compartmental ligand N,N′-bis(3-methoxysalicylidene)ethylenediamine (H2L), the Eu and Zn atoms are triply bridged by two phenolate O atoms of the Schiff base ligand and one nitrate ion. The five-coordinate Zn atom is in a square-pyramidal geometry with the donor centers of two imine N atoms, two phenolate O atoms and one of the bridging nitrate O atoms. The EuIII center has a ninefold coordination environment of O atoms, involving the phenolate O atoms, two methoxy O atoms, two O atoms from two nitrate ions and one from the bridging nitrate ion. Weak intermolecular C—H...O interactions generate a two-dimensional double-layer structure.