(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine
In the title compound, C26H27BrN2O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bisectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)&#...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812028887 |
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doaj-44f3c8f30471431386409e1e16c9b9c52020-11-25T03:27:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2267o226710.1107/S1600536812028887(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imineChennan RamalinganSeik Weng NgEdward R. T. TiekinkIn the title compound, C26H27BrN2O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bisectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromobenzene ring. The latter is coplanar with the methoxy(methylidene)amine fragment [N—O—C—C torsion angle = −171.7 (2)°]. Linear supramolecular chains, approximately along [112], sustained by C—H...π interactions, feature in the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812028887 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink |
| spellingShingle |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink (4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine Acta Crystallographica Section E |
| author_facet |
Chennan Ramalingan Seik Weng Ng Edward R. T. Tiekink |
| author_sort |
Chennan Ramalingan |
| title |
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_short |
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_full |
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_fullStr |
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_full_unstemmed |
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| title_sort |
(4e)-n-[(2-bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-07-01 |
| description |
In the title compound, C26H27BrN2O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bisectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromobenzene ring. The latter is coplanar with the methoxy(methylidene)amine fragment [N—O—C—C torsion angle = −171.7 (2)°]. Linear supramolecular chains, approximately along [112], sustained by C—H...π interactions, feature in the crystal packing. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812028887 |
| work_keys_str_mv |
AT chennanramalingan 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine AT seikwengng 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine AT edwardrttiekink 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine |
| _version_ |
1724589739301928960 |