| Summary: | Calcified roasting followed by dilute sulfuric acid leaching is a promising process for cleaner vanadium extraction from converter vanadium slag. However, some impurities, like Ca, Mg, Mn, Si and Al, also transfer into the leaching solution, accompanying V during the dilute sulfuric acid leaching, leading to the product of vanadium pentoxide prepared from this acidic vanadium-bearing solution, inferior to the product from the traditional process of sodium roasting and water leaching. A chemical precipitation method was firstly proposed to purify this acidic vanadium-bearing solution with a new prepared remover of MnNH<sub>4</sub>F<sub>3</sub>, which combines neutralization and fluoride precipitation into one operational step to remove impurities of Ca<sup>2+</sup>, Mg <sup>2+</sup>, Al<sup>3+</sup> and Si<sup>4+</sup> in an acidic pH range, simultaneously. Effecting factors involved in the purification process were investigated. It was found that removals of Ca, Mg and Al were all over 95% and around 55% of Si was removed as well at stirring speed of 200 rpm, adding coefficient of 1.6, temperature of 50 °C, reaction time of 30 min and pH of 4.50 ± 0.05, while the loss of vanadium was kept lower than 5%, which was attributed to the reason that the purification reactions mainly proceeded on the surface of the remover. Adding flocculant of polyacrylamide was conductive to accelerating sedimentation of the precipitate and reducing the loss of vanadium. Meanwhile, the filter aid of diatomaceous could improve the filtration performance of the slurry. Ammonium persulfate could effectively oxidize and separate Mn<sup>2+</sup> in the form of MnO<sub>2</sub> from the vanadium-bearing solution which had been treated by MnNH<sub>4</sub>F<sub>3</sub>, but performed less selectivity over Mn<sup>2+</sup>, and the loss of vanadium was unacceptable. The product of vanadium pentoxide prepared from the purified vanadium-containing solution satisfied the requirements for the standard of grade 98.
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