catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]

catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]

The title compound, {[Cu(C10H14N4Se)2(H2O)](BF4)2·2C18H15PO·H2O}n, has a polymeric structure where each CuII ion adopts a square-pyramidal coordination constituted by four N atoms of pyrazole moieties in the equatorial plane and an axial O atom of a water molecule. A pair o...

Full description

Bibliographic Details
Main Authors: Maksym Seredyuk, Kateryna O. Znovjyak, Yurii S. Moroz, Vadim A. Pavlenko, Igor O. Fritsky
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810012997
id doaj-466362d7eb1b4cc6a49f4c4772cb953f
record_format Article
spelling doaj-466362d7eb1b4cc6a49f4c4772cb953f2020-11-24T21:29:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m527m52710.1107/S1600536810012997catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]Maksym SeredyukKateryna O. ZnovjyakYurii S. MorozVadim A. PavlenkoIgor O. FritskyThe title compound, {[Cu(C10H14N4Se)2(H2O)](BF4)2·2C18H15PO·H2O}n, has a polymeric structure where each CuII ion adopts a square-pyramidal coordination constituted by four N atoms of pyrazole moieties in the equatorial plane and an axial O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridges the CuII centres into a chain extending along the c axis. The water molecules, anions and triphenylphosphine oxide molecules are involved in intermolecular hydrogen bonding, which links the chains into a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536810012997
collection DOAJ
language English
format Article
sources DOAJ
author Maksym Seredyuk
Kateryna O. Znovjyak
Yurii S. Moroz
Vadim A. Pavlenko
Igor O. Fritsky
spellingShingle Maksym Seredyuk
Kateryna O. Znovjyak
Yurii S. Moroz
Vadim A. Pavlenko
Igor O. Fritsky
catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
Acta Crystallographica Section E
author_facet Maksym Seredyuk
Kateryna O. Znovjyak
Yurii S. Moroz
Vadim A. Pavlenko
Igor O. Fritsky
author_sort Maksym Seredyuk
title catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
title_short catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
title_full catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
title_fullStr catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
title_full_unstemmed catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
title_sort catena-poly[[[aquacopper(ii)]bis[μ-bis(3,5-dimethyl-1h-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description The title compound, {[Cu(C10H14N4Se)2(H2O)](BF4)2·2C18H15PO·H2O}n, has a polymeric structure where each CuII ion adopts a square-pyramidal coordination constituted by four N atoms of pyrazole moieties in the equatorial plane and an axial O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridges the CuII centres into a chain extending along the c axis. The water molecules, anions and triphenylphosphine oxide molecules are involved in intermolecular hydrogen bonding, which links the chains into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810012997
work_keys_str_mv AT maksymseredyuk catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebistetrafluoridoboratebistriphenylphosphineoxidemonohydrate
AT katerynaoznovjyak catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebistetrafluoridoboratebistriphenylphosphineoxidemonohydrate
AT yuriismoroz catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebistetrafluoridoboratebistriphenylphosphineoxidemonohydrate
AT vadimapavlenko catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebistetrafluoridoboratebistriphenylphosphineoxidemonohydrate
AT igorofritsky catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebistetrafluoridoboratebistriphenylphosphineoxidemonohydrate
_version_ 1725967564893323264

Similar Items