Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

The title complex, [Nd(C6H6NO3S)2(C12H8N2)2(H2O)3]NO3·4H2O, comprises a mononuclear cation, an NO3− anion and two uncoordinated water molecules; the NdIII cation, one coordinated water molecule, and the NO3− anion each lie on a twofold axis of symmetry. The N...

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Main Authors: Peng Ma, Miao-Ling Huang, Kai-Han Chen
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810023445
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spelling doaj-4674510a675d43a898e9d6a39e41c6712020-11-25T00:50:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m833m83310.1107/S1600536810023445Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydratePeng MaMiao-Ling HuangKai-Han ChenThe title complex, [Nd(C6H6NO3S)2(C12H8N2)2(H2O)3]NO3·4H2O, comprises a mononuclear cation, an NO3− anion and two uncoordinated water molecules; the NdIII cation, one coordinated water molecule, and the NO3− anion each lie on a twofold axis of symmetry. The NdIII ion exhibits an NdN4O5 coordination environment comprising two O atoms of two monodentate 4-aminobenzenesulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H...O, O—H...N and N—H...O hydrogen-bonding interactions http://scripts.iucr.org/cgi-bin/paper?S1600536810023445
collection DOAJ
language English
format Article
sources DOAJ
author Peng Ma
Miao-Ling Huang
Kai-Han Chen
spellingShingle Peng Ma
Miao-Ling Huang
Kai-Han Chen
Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
Acta Crystallographica Section E
author_facet Peng Ma
Miao-Ling Huang
Kai-Han Chen
author_sort Peng Ma
title Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_short Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_full Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_fullStr Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_full_unstemmed Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_sort bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(iii) nitrate tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description The title complex, [Nd(C6H6NO3S)2(C12H8N2)2(H2O)3]NO3·4H2O, comprises a mononuclear cation, an NO3− anion and two uncoordinated water molecules; the NdIII cation, one coordinated water molecule, and the NO3− anion each lie on a twofold axis of symmetry. The NdIII ion exhibits an NdN4O5 coordination environment comprising two O atoms of two monodentate 4-aminobenzenesulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H...O, O—H...N and N—H...O hydrogen-bonding interactions
url http://scripts.iucr.org/cgi-bin/paper?S1600536810023445
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AT miaolinghuang bis4aminobenzenesulfonatotriaquabis110phenanthrolineneodymiumiiinitratetetrahydrate
AT kaihanchen bis4aminobenzenesulfonatotriaquabis110phenanthrolineneodymiumiiinitratetetrahydrate
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