catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′]
In the structure of the polymeric title compound, [ZnCl2(C12H18N4)]n or [ZnCl2(L)]n, where L = 1,1′-(hexane-1,6-diyl)diimidazole, the ZnII centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetrahedral geometry. The organic ligand...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809037696 |
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doaj-47fa88761f5048848827f37a3335c48f2020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1239m123910.1107/S1600536809037696catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′]Wen-Li BaoIn the structure of the polymeric title compound, [ZnCl2(C12H18N4)]n or [ZnCl2(L)]n, where L = 1,1′-(hexane-1,6-diyl)diimidazole, the ZnII centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetrahedral geometry. The organic ligand links adjacent metals to form a polymeric chain along the c axis. The chains are further connected into layers parallel to the bc plane by intermolecular C—H...Cl hydrogen bonds. Two C atoms of the central hexyl chain are disordered over two positions with site-occupancy factors of 0.5. http://scripts.iucr.org/cgi-bin/paper?S1600536809037696 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Wen-Li Bao |
| spellingShingle |
Wen-Li Bao catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] Acta Crystallographica Section E |
| author_facet |
Wen-Li Bao |
| author_sort |
Wen-Li Bao |
| title |
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] |
| title_short |
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] |
| title_full |
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] |
| title_fullStr |
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] |
| title_full_unstemmed |
catena-Poly[[dichloridozinc(II)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2N3:N3′] |
| title_sort |
catena-poly[[dichloridozinc(ii)]-μ-1,1′-(hexane-1,6-diyl)diimidazole-κ2n3:n3′] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-10-01 |
| description |
In the structure of the polymeric title compound, [ZnCl2(C12H18N4)]n or [ZnCl2(L)]n, where L = 1,1′-(hexane-1,6-diyl)diimidazole, the ZnII centre is coordinated by two N atoms of two different L ligands and by two chloride anions in a distorted tetrahedral geometry. The organic ligand links adjacent metals to form a polymeric chain along the c axis. The chains are further connected into layers parallel to the bc plane by intermolecular C—H...Cl hydrogen bonds. Two C atoms of the central hexyl chain are disordered over two positions with site-occupancy factors of 0.5. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809037696 |
| work_keys_str_mv |
AT wenlibao catenapolydichloridozinciiamp95611amp8242hexane16diyldiimidazoleamp9542n3n3amp8242 |
| _version_ |
1725872493138280448 |