2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole
The title compound, C17H14ClN3O4, was prepared by the Huisgen reaction of 4-chloro-2-nitrobenzoyl chloride and 5-(4-propyloxyphenyl)tetrazole. The diphenyl-1,3,4-oxadiazole unit is nearly planar. The oxadiazole ring is inclined to the 4-chloro-2-nitrophenyl ring by 7.77 (8)°, and by 7.93 (8)° to the...
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International Union of Crystallography
2016-11-01
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doaj-4864c94b73e7473e9b2a97466db353422020-11-25T01:47:19ZengInternational Union of CrystallographyIUCrData2414-31462016-11-01111x16178210.1107/S241431461601782Xsu40932-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazoleDaniel Limbach0Heiner Detert1Dieter Schollmeyer2University of Mainz, Institut for Organic Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyUniversity of Mainz, Institut for Organic Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyUniversity of Mainz, Institut for Organic Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyThe title compound, C17H14ClN3O4, was prepared by the Huisgen reaction of 4-chloro-2-nitrobenzoyl chloride and 5-(4-propyloxyphenyl)tetrazole. The diphenyl-1,3,4-oxadiazole unit is nearly planar. The oxadiazole ring is inclined to the 4-chloro-2-nitrophenyl ring by 7.77 (8)°, and by 7.93 (8)° to the 4-propyloxyphenyl ring. The benzene rings are inclined to one another by 1.32 (7)°. The nitro group is twisted out of the plane of the benzene ring to which it is attached by 73.59 (16)°. The propoxy chain mean plane is inclined to the benzene ring to which it is attached by 4.46 (13)°. In the crystal, C—H...O and C—H...N hydrogen bonds connect the molecules, forming ribbons propagating along the b-axis direction. The ribbons are linked by C—H...π interactions, forming slabs parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S241431461601782Xcrystal structure1,3,4-oxadiazolenitro compoundhydrogen bondingC—H...π interactions |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Daniel Limbach Heiner Detert Dieter Schollmeyer |
spellingShingle |
Daniel Limbach Heiner Detert Dieter Schollmeyer 2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole IUCrData crystal structure 1,3,4-oxadiazole nitro compound hydrogen bonding C—H...π interactions |
author_facet |
Daniel Limbach Heiner Detert Dieter Schollmeyer |
author_sort |
Daniel Limbach |
title |
2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
title_short |
2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
title_full |
2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
title_fullStr |
2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
title_full_unstemmed |
2-(4-Chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
title_sort |
2-(4-chloro-2-nitrophenyl)-5-[4-(propyloxy)phenyl]-1,3,4-oxadiazole |
publisher |
International Union of Crystallography |
series |
IUCrData |
issn |
2414-3146 |
publishDate |
2016-11-01 |
description |
The title compound, C17H14ClN3O4, was prepared by the Huisgen reaction of 4-chloro-2-nitrobenzoyl chloride and 5-(4-propyloxyphenyl)tetrazole. The diphenyl-1,3,4-oxadiazole unit is nearly planar. The oxadiazole ring is inclined to the 4-chloro-2-nitrophenyl ring by 7.77 (8)°, and by 7.93 (8)° to the 4-propyloxyphenyl ring. The benzene rings are inclined to one another by 1.32 (7)°. The nitro group is twisted out of the plane of the benzene ring to which it is attached by 73.59 (16)°. The propoxy chain mean plane is inclined to the benzene ring to which it is attached by 4.46 (13)°. In the crystal, C—H...O and C—H...N hydrogen bonds connect the molecules, forming ribbons propagating along the b-axis direction. The ribbons are linked by C—H...π interactions, forming slabs parallel to the ab plane. |
topic |
crystal structure 1,3,4-oxadiazole nitro compound hydrogen bonding C—H...π interactions |
url |
http://scripts.iucr.org/cgi-bin/paper?S241431461601782X |
work_keys_str_mv |
AT daniellimbach 24chloro2nitrophenyl54propyloxyphenyl134oxadiazole AT heinerdetert 24chloro2nitrophenyl54propyloxyphenyl134oxadiazole AT dieterschollmeyer 24chloro2nitrophenyl54propyloxyphenyl134oxadiazole |
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1725015046431440896 |