Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]

Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]

The asymmetric unit of the polymeric title compound, [Mg3(C9H3O6)2(C3H7NO)4]n, contains three MgII ions bridged by carboxylate O atoms from two fully deprotonated benzene-1,3,5-tricarboxylate (BTC) trianions and four metal-coordinated dimethylformamide (DMF) molecules. One MgII ion is octahedrally c...

Full description

Bibliographic Details
Main Authors: Katarzyna Łuczyńska-Szymczak, Wojciech Starosta, Janusz Leciejewicz
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812023240
id doaj-486c4532c5dc45c898128e711bdf7d82
record_format Article
spelling doaj-486c4532c5dc45c898128e711bdf7d822020-11-25T01:15:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m852m85310.1107/S1600536812023240Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]Katarzyna Łuczyńska-SzymczakWojciech StarostaJanusz LeciejewiczThe asymmetric unit of the polymeric title compound, [Mg3(C9H3O6)2(C3H7NO)4]n, contains three MgII ions bridged by carboxylate O atoms from two fully deprotonated benzene-1,3,5-tricarboxylate (BTC) trianions and four metal-coordinated dimethylformamide (DMF) molecules. One MgII ion is octahedrally coordinated by six carboxylate O atoms. The other two cations are each octahedrally coordinated by four carboxylate O atoms and two O atoms donated by two DMF molecules: in one, the DMF molecules are cis and in the other they are trans. The three MgII octahedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812023240
collection DOAJ
language English
format Article
sources DOAJ
author Katarzyna Łuczyńska-Szymczak
Wojciech Starosta
Janusz Leciejewicz
spellingShingle Katarzyna Łuczyńska-Szymczak
Wojciech Starosta
Janusz Leciejewicz
Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
Acta Crystallographica Section E
author_facet Katarzyna Łuczyńska-Szymczak
Wojciech Starosta
Janusz Leciejewicz
author_sort Katarzyna Łuczyńska-Szymczak
title Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
title_short Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
title_full Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
title_fullStr Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
title_full_unstemmed Poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7O1,O1′:O1′:O3:O3′:O5:O5′)tetrakis(dimethylformamide-κO)trimagnesium(II)]
title_sort poly[bis(μ6-benzene-1,3,5-tricarboxylato-κ7o1,o1′:o1′:o3:o3′:o5:o5′)tetrakis(dimethylformamide-κo)trimagnesium(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The asymmetric unit of the polymeric title compound, [Mg3(C9H3O6)2(C3H7NO)4]n, contains three MgII ions bridged by carboxylate O atoms from two fully deprotonated benzene-1,3,5-tricarboxylate (BTC) trianions and four metal-coordinated dimethylformamide (DMF) molecules. One MgII ion is octahedrally coordinated by six carboxylate O atoms. The other two cations are each octahedrally coordinated by four carboxylate O atoms and two O atoms donated by two DMF molecules: in one, the DMF molecules are cis and in the other they are trans. The three MgII octahedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812023240
work_keys_str_mv AT katarzynaamp321uczyamp324skaszymczak polybisamp9566benzene135tricarboxylatoamp9547o1o1amp8242o1amp8242o3o3amp8242o5o5amp8242tetrakisdimethylformamideamp954otrimagnesiumii
AT wojciechstarosta polybisamp9566benzene135tricarboxylatoamp9547o1o1amp8242o1amp8242o3o3amp8242o5o5amp8242tetrakisdimethylformamideamp954otrimagnesiumii
AT januszleciejewicz polybisamp9566benzene135tricarboxylatoamp9547o1o1amp8242o1amp8242o3o3amp8242o5o5amp8242tetrakisdimethylformamideamp954otrimagnesiumii
_version_ 1725153852678733824

Similar Items