The Growth of Photoactive Porphyrin-Based MOF Thin Films Using the Liquid-Phase Epitaxy Approach and Their Optoelectronic Properties

• Main Authors: Guy Olivier Ngongang Ndjawa, Mohamed R. Tchalala, Osama Shekhah, Jafar I. Khan, Ahmed E. Mansour, Justyna Czaban-Jóźwiak, Lukasz J. Weselinski, Hassan Ait Ahsaine, Aram Amassian, Mohamed Eddaoudi
• Format: Article
• Language: English
• Published: MDPI AG 2019-08-01
• Series: Materials
• Subjects: metal-organic framework; thin films; photoactive; optolectronic and liquid-phase epitaxy
• Online Access: https://www.mdpi.com/1996-1944/12/15/2457

This study reports on the optoelectronic properties of porphyrin-based metal−organic framework (MOF) thin films fabricated by a facile liquid-phase epitaxy approach. This approach affords the growth of MOF thin films that are free of morphological imperfections, more suitable for optoelectronic applications. Chemical modifications such as the porphyrin ligand metallation have been found to preserve the morphology of the grown films making this approach particularly suitable for molecular alteration of MOF thin film optoelectronic properties without compromising its mesoscale morphology significantly. Particularly, the metallation of the ligand was found to be effective to tune the MOF bandgap. These porphyrin-based MOF thin films were shown to function effectively as donor layers in solar cells based on a Fullerene-C₆₀ acceptor. The ability to fabricate MOF solar cells free of a liquid-phase acceptor greatly simplifies device fabrication and enables pairing of MOFs as light absorbers with a wide range of acceptors including non-fullerene acceptors.