Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron

Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron

In the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...&...

Full description

Bibliographic Details
Main Authors: Daisuke Urakami, Katsuya Inoue, Shinya Hayami
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809036071
id doaj-491e652dd7c0488f93e4c52981fc7457
record_format Article
spelling doaj-491e652dd7c0488f93e4c52981fc74572020-11-24T20:48:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510o2425o242510.1107/S1600536809036071Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boronDaisuke UrakamiKatsuya InoueShinya HayamiIn the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...π interactions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°. http://scripts.iucr.org/cgi-bin/paper?S1600536809036071
collection DOAJ
language English
format Article
sources DOAJ
author Daisuke Urakami
Katsuya Inoue
Shinya Hayami
spellingShingle Daisuke Urakami
Katsuya Inoue
Shinya Hayami
Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
Acta Crystallographica Section E
author_facet Daisuke Urakami
Katsuya Inoue
Shinya Hayami
author_sort Daisuke Urakami
title Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_short Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_full Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_fullStr Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_full_unstemmed Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
title_sort triphenyl{(e)-4-[4-(phenyldiazenyl)phenyl]-4h-1,2,4-triazol-1-yl}boron
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description In the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds. The crystal structure features very weak C—H...π interactions. The dihedral angles between the central benzene ring and the terminal rings in the heterocycle are 62.64, 73.54 and 61.60°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809036071
work_keys_str_mv AT daisukeurakami triphenyle44phenyldiazenylphenyl4h124triazol1ylboron
AT katsuyainoue triphenyle44phenyldiazenylphenyl4h124triazol1ylboron
AT shinyahayami triphenyle44phenyldiazenylphenyl4h124triazol1ylboron
_version_ 1716807523166584832

Similar Items