Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability
Reactive surfactants (surfmers), which are covalently attached to the surface of sub-micron sized polymer particles during emulsion polymerisation, are applied to tailor the surface functionality of polymer particles for an application of choice. We present a systematic study on the use of oligoglyc...
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doaj-4956cac922654f70bb5ef7cc7e0dc2242020-11-25T03:21:34ZengMDPI AGPolymers2073-43602020-07-01121557155710.3390/polym12071557Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal StabilityKim Waulthers0Ryan van Zandvoort1Sam Castermans2Jeroen Welzen3Evelien Baeten4Kathleen Stout5Helmut Keul6Daniel Mann7Pascal Buskens8Zuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsThe Netherlands Organisation for Applied Scientific Research (TNO), High Tech Campus 25, 5656AE Eindhoven, The NetherlandsZuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsZuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsZuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsZuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsDWI–Leibniz Institute for Interactive Materials, Forckenbeckstrasse 50, 52056 Aachen, GermanyThe Netherlands Organisation for Applied Scientific Research (TNO), High Tech Campus 25, 5656AE Eindhoven, The NetherlandsZuyd University of Applied Sciences, Nieuw Eyckholt 300, 6400AN Heerlen, The NetherlandsReactive surfactants (surfmers), which are covalently attached to the surface of sub-micron sized polymer particles during emulsion polymerisation, are applied to tailor the surface functionality of polymer particles for an application of choice. We present a systematic study on the use of oligoglycidol-functionalised styrene macromolecules as surfmers in the emulsion polymerization of styrene. Firstly, we report the impact of the surfmer concentration on the particle size for polymerisations performed above and below the critical micelle concentration. Secondly, we report the influence of the oligoglycidol chain length on the particle size. Thirdly, we conducted experiments to analyse the influence of the surfmer concentration and its chain length on the colloidal stability of the aqueous polystyrene nanoparticles in sodium chloride solutions. We demonstrated that the size of polystyrene particles could be influenced by changing both the surfmer concentration and its chain length. Furthermore, we showed that the colloidal stability of the oligoglycidol-functionalized polystyrene particles is dependent on the particle size, and not directly related to the oligoglycidol chain length.https://www.mdpi.com/2073-4360/12/7/1557polymer nanoparticlesemulsion polymerizationstyrenereactive surfactantsurfmeroligoglycidol |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kim Waulthers Ryan van Zandvoort Sam Castermans Jeroen Welzen Evelien Baeten Kathleen Stout Helmut Keul Daniel Mann Pascal Buskens |
spellingShingle |
Kim Waulthers Ryan van Zandvoort Sam Castermans Jeroen Welzen Evelien Baeten Kathleen Stout Helmut Keul Daniel Mann Pascal Buskens Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability Polymers polymer nanoparticles emulsion polymerization styrene reactive surfactant surfmer oligoglycidol |
author_facet |
Kim Waulthers Ryan van Zandvoort Sam Castermans Jeroen Welzen Evelien Baeten Kathleen Stout Helmut Keul Daniel Mann Pascal Buskens |
author_sort |
Kim Waulthers |
title |
Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability |
title_short |
Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability |
title_full |
Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability |
title_fullStr |
Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability |
title_full_unstemmed |
Oligoglycidol-Functionalised Styrene Macromolecules as Reactive Surfactants in the Emulsion Polymerisation of Styrene: The Impact of Chain Length and Concentration on Particle Size and Colloidal Stability |
title_sort |
oligoglycidol-functionalised styrene macromolecules as reactive surfactants in the emulsion polymerisation of styrene: the impact of chain length and concentration on particle size and colloidal stability |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2020-07-01 |
description |
Reactive surfactants (surfmers), which are covalently attached to the surface of sub-micron sized polymer particles during emulsion polymerisation, are applied to tailor the surface functionality of polymer particles for an application of choice. We present a systematic study on the use of oligoglycidol-functionalised styrene macromolecules as surfmers in the emulsion polymerization of styrene. Firstly, we report the impact of the surfmer concentration on the particle size for polymerisations performed above and below the critical micelle concentration. Secondly, we report the influence of the oligoglycidol chain length on the particle size. Thirdly, we conducted experiments to analyse the influence of the surfmer concentration and its chain length on the colloidal stability of the aqueous polystyrene nanoparticles in sodium chloride solutions. We demonstrated that the size of polystyrene particles could be influenced by changing both the surfmer concentration and its chain length. Furthermore, we showed that the colloidal stability of the oligoglycidol-functionalized polystyrene particles is dependent on the particle size, and not directly related to the oligoglycidol chain length. |
topic |
polymer nanoparticles emulsion polymerization styrene reactive surfactant surfmer oligoglycidol |
url |
https://www.mdpi.com/2073-4360/12/7/1557 |
work_keys_str_mv |
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