Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)

Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)

The asymmetric unit of the title compound, [Li4(C5H3N2O2)4(H2O)4], contains two symmetry-independent LiI ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two LiI ions are bridged by two carboxylate O atoms from t...

Full description

Bibliographic Details
Main Authors: Wojciech Starosta, Janusz Leciejewicz
Format: Article
Language:English
Published: International Union of Crystallography 2012-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681203142X
id doaj-49cc406e060144b6b614ec20040f0a1f
record_format Article
spelling doaj-49cc406e060144b6b614ec20040f0a1f2020-11-25T00:12:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688m1065m106610.1107/S160053681203142XBis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)Wojciech StarostaJanusz LeciejewiczThe asymmetric unit of the title compound, [Li4(C5H3N2O2)4(H2O)4], contains two symmetry-independent LiI ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two LiI ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the LiI ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.http://scripts.iucr.org/cgi-bin/paper?S160053681203142X
collection DOAJ
language English
format Article
sources DOAJ
author Wojciech Starosta
Janusz Leciejewicz
spellingShingle Wojciech Starosta
Janusz Leciejewicz
Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
Acta Crystallographica Section E
author_facet Wojciech Starosta
Janusz Leciejewicz
author_sort Wojciech Starosta
title Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
title_short Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
title_full Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
title_fullStr Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
title_full_unstemmed Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
title_sort bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-08-01
description The asymmetric unit of the title compound, [Li4(C5H3N2O2)4(H2O)4], contains two symmetry-independent LiI ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two LiI ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the LiI ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.
url http://scripts.iucr.org/cgi-bin/paper?S160053681203142X
work_keys_str_mv AT wojciechstarosta bisamp9563pyrimidine4carboxylatobisamp9562pyrimidine4carboxylatotetrakisaqualithium
AT januszleciejewicz bisamp9563pyrimidine4carboxylatobisamp9562pyrimidine4carboxylatotetrakisaqualithium
_version_ 1725399059181600768

Similar Items