Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties

The discovery of ferrocene is often associated with the rapid growth of organometallic chemistry. Dendrimers are highly branched macromolecules that can be functionalized at will at all levels of their structure. The functionalization of dendrimers with ferrocene derivatives can be carried out easil...

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Main Authors:	Cédric-Olivier Turrin, Eric Manoury, Anne-Marie Caminade
Format:	Article
Language:	English
Published:	MDPI AG 2020-01-01
Series:	Molecules
Subjects:	ferrocene dendrimer catalysis electrochemistry
Online Access:	https://www.mdpi.com/1420-3049/25/3/447

id	doaj-49d0f9d4656b4c26860bad36e3258a42
record_format	Article
spelling	doaj-49d0f9d4656b4c26860bad36e3258a422020-11-25T01:12:58ZengMDPI AGMolecules1420-30492020-01-0125344710.3390/molecules25030447molecules25030447Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic PropertiesCédric-Olivier Turrin0Eric Manoury1Anne-Marie Caminade2Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, BP 44099, 31077 Toulouse CEDEX 4, FranceLaboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, BP 44099, 31077 Toulouse CEDEX 4, FranceLaboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, BP 44099, 31077 Toulouse CEDEX 4, FranceThe discovery of ferrocene is often associated with the rapid growth of organometallic chemistry. Dendrimers are highly branched macromolecules that can be functionalized at will at all levels of their structure. The functionalization of dendrimers with ferrocene derivatives can be carried out easily as terminal functions on the surface, but also at the core, or at one or several layers inside the structure. This review will focus on phosphorhydrazone dendrimers functionalized with ferrocene derivatives, on the surface, at the core, at all layers or within a single layer inside the structure. The first part will describe the synthesis; the second part will concern the electrochemical properties; and the last part will give several examples concerning catalysis, with complexes of ferrocenyl phosphines used as terminal functions of dendrimers.https://www.mdpi.com/1420-3049/25/3/447ferrocenedendrimercatalysiselectrochemistry
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Cédric-Olivier Turrin Eric Manoury Anne-Marie Caminade
spellingShingle	Cédric-Olivier Turrin Eric Manoury Anne-Marie Caminade Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties Molecules ferrocene dendrimer catalysis electrochemistry
author_facet	Cédric-Olivier Turrin Eric Manoury Anne-Marie Caminade
author_sort	Cédric-Olivier Turrin
title	Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties
title_short	Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties
title_full	Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties
title_fullStr	Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties
title_full_unstemmed	Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties
title_sort	ferrocenyl phosphorhydrazone dendrimers synthesis, and electrochemical and catalytic properties
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2020-01-01
description	The discovery of ferrocene is often associated with the rapid growth of organometallic chemistry. Dendrimers are highly branched macromolecules that can be functionalized at will at all levels of their structure. The functionalization of dendrimers with ferrocene derivatives can be carried out easily as terminal functions on the surface, but also at the core, or at one or several layers inside the structure. This review will focus on phosphorhydrazone dendrimers functionalized with ferrocene derivatives, on the surface, at the core, at all layers or within a single layer inside the structure. The first part will describe the synthesis; the second part will concern the electrochemical properties; and the last part will give several examples concerning catalysis, with complexes of ferrocenyl phosphines used as terminal functions of dendrimers.
topic	ferrocene dendrimer catalysis electrochemistry
url	https://www.mdpi.com/1420-3049/25/3/447
work_keys_str_mv	AT cedricolivierturrin ferrocenylphosphorhydrazonedendrimerssynthesisandelectrochemicalandcatalyticproperties AT ericmanoury ferrocenylphosphorhydrazonedendrimerssynthesisandelectrochemicalandcatalyticproperties AT annemariecaminade ferrocenylphosphorhydrazonedendrimerssynthesisandelectrochemicalandcatalyticproperties
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Ferrocenyl Phosphorhydrazone Dendrimers Synthesis, and Electrochemical and Catalytic Properties

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