Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)

Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)

In the title compound, [Ru(C9H10BN6)Cl(C3H4N2)(C18H15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydridotrispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenylphosphine ligand, resulting in a distorted RuClP...

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Main Authors: Chiung-Cheng Huang, Han-Gung Chen, Yih Hsing Lo, Li-Sheng Hsu, Chia-Her Lin
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810021525
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spelling doaj-4afd8af106d04c61876faca6a8b04e4d2020-11-25T01:36:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m795m79610.1107/S1600536810021525Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)Chiung-Cheng HuangHan-Gung ChenYih Hsing LoLi-Sheng HsuChia-Her LinIn the title compound, [Ru(C9H10BN6)Cl(C3H4N2)(C18H15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydridotrispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenylphosphine ligand, resulting in a distorted RuClPN4 octahedral coordination for the metal ion: the tridentate N atoms occupy one octahedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intramolecular N—H...Cl hydrogen bond generates an S(5) ring. http://scripts.iucr.org/cgi-bin/paper?S1600536810021525
collection DOAJ
language English
format Article
sources DOAJ
author Chiung-Cheng Huang
Han-Gung Chen
Yih Hsing Lo
Li-Sheng Hsu
Chia-Her Lin
spellingShingle Chiung-Cheng Huang
Han-Gung Chen
Yih Hsing Lo
Li-Sheng Hsu
Chia-Her Lin
Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
Acta Crystallographica Section E
author_facet Chiung-Cheng Huang
Han-Gung Chen
Yih Hsing Lo
Li-Sheng Hsu
Chia-Her Lin
author_sort Chiung-Cheng Huang
title Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
title_short Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
title_full Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
title_fullStr Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
title_full_unstemmed Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole-κN2)(triphenylphosphine-κP)ruthenium(II)
title_sort chlorido[hydridotris(pyrazol-1-yl-κn2)borato](1h-pyrazole-κn2)(triphenylphosphine-κp)ruthenium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the title compound, [Ru(C9H10BN6)Cl(C3H4N2)(C18H15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydridotrispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenylphosphine ligand, resulting in a distorted RuClPN4 octahedral coordination for the metal ion: the tridentate N atoms occupy one octahedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intramolecular N—H...Cl hydrogen bond generates an S(5) ring.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810021525
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AT hangungchen chloridohydridotrispyrazol1ylamp954n2borato1hpyrazoleamp954n2triphenylphosphineamp954prutheniumii
AT yihhsinglo chloridohydridotrispyrazol1ylamp954n2borato1hpyrazoleamp954n2triphenylphosphineamp954prutheniumii
AT lishenghsu chloridohydridotrispyrazol1ylamp954n2borato1hpyrazoleamp954n2triphenylphosphineamp954prutheniumii
AT chiaherlin chloridohydridotrispyrazol1ylamp954n2borato1hpyrazoleamp954n2triphenylphosphineamp954prutheniumii
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