Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors

In this work, we reported a moss-derived biomass porous carbon (MPC) as a bi-functional electrode material for both the lithium–sulfur battery and the supercapacitor. The MPC was prepared from a high-temperature calcination procedure using the moss as the carbonaceous precursor. Using NaOH...

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Main Authors: Wen Lei, Haipeng Liu, Junlei Xiao, Yang Wang, Liangxu Lin
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/9/1/84
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spelling doaj-4b4557b8cfd840549eb092e4ddbb80f92020-11-24T23:01:49ZengMDPI AGNanomaterials2079-49912019-01-01918410.3390/nano9010084nano9010084Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and SupercapacitorsWen Lei0Haipeng Liu1Junlei Xiao2Yang Wang3Liangxu Lin4The State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaThe State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaThe State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaHefei Guoxuan High-Tech Power Energy Co., Ltd., 599 Daihe Road, Hefei 230000, ChinaThe State Key Laboratory of Refractories and Metallurgy, and Institute of Advanced Materials and Nanotechnology, Wuhan University of Science and Technology, Wuhan 430081, ChinaIn this work, we reported a moss-derived biomass porous carbon (MPC) as a bi-functional electrode material for both the lithium–sulfur battery and the supercapacitor. The MPC was prepared from a high-temperature calcination procedure using the moss as the carbonaceous precursor. Using NaOH, the MPC was activated to give a mesoporous structure with a high specific surface area (1057.1 m2 g−1) and large pore volume (0.72 cm3 g−1). When it was used as the cathode material in lithium–sulfur batteries, the MPC material realized a sulfur loading and exhibited a remarkably improved electrochemical performance, i.e., a high discharge capacity of 1070 mAh g−1 at 0.1 C. This activated MPC also worked well as a capacitive electrode in supercapacitors, demonstrating a high specific capacitance of 332 F g−1 (scan rate of 1.0 A g−1) and a high capacity retention > 97% in a long-term cycle of 1000 charge/discharges. This work demonstrated a facile method for the utilization of activated waste biomass material for future clean energy applications.http://www.mdpi.com/2079-4991/9/1/84mossbiomass derived carbonlithium–sulfur batteriessupercapacitors
collection DOAJ
language English
format Article
sources DOAJ
author Wen Lei
Haipeng Liu
Junlei Xiao
Yang Wang
Liangxu Lin
spellingShingle Wen Lei
Haipeng Liu
Junlei Xiao
Yang Wang
Liangxu Lin
Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
Nanomaterials
moss
biomass derived carbon
lithium–sulfur batteries
supercapacitors
author_facet Wen Lei
Haipeng Liu
Junlei Xiao
Yang Wang
Liangxu Lin
author_sort Wen Lei
title Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
title_short Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
title_full Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
title_fullStr Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
title_full_unstemmed Moss-Derived Mesoporous Carbon as Bi-Functional Electrode Materials for Lithium–Sulfur Batteries and Supercapacitors
title_sort moss-derived mesoporous carbon as bi-functional electrode materials for lithium–sulfur batteries and supercapacitors
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2019-01-01
description In this work, we reported a moss-derived biomass porous carbon (MPC) as a bi-functional electrode material for both the lithium–sulfur battery and the supercapacitor. The MPC was prepared from a high-temperature calcination procedure using the moss as the carbonaceous precursor. Using NaOH, the MPC was activated to give a mesoporous structure with a high specific surface area (1057.1 m2 g−1) and large pore volume (0.72 cm3 g−1). When it was used as the cathode material in lithium–sulfur batteries, the MPC material realized a sulfur loading and exhibited a remarkably improved electrochemical performance, i.e., a high discharge capacity of 1070 mAh g−1 at 0.1 C. This activated MPC also worked well as a capacitive electrode in supercapacitors, demonstrating a high specific capacitance of 332 F g−1 (scan rate of 1.0 A g−1) and a high capacity retention > 97% in a long-term cycle of 1000 charge/discharges. This work demonstrated a facile method for the utilization of activated waste biomass material for future clean energy applications.
topic moss
biomass derived carbon
lithium–sulfur batteries
supercapacitors
url http://www.mdpi.com/2079-4991/9/1/84
work_keys_str_mv AT wenlei mossderivedmesoporouscarbonasbifunctionalelectrodematerialsforlithiumsulfurbatteriesandsupercapacitors
AT haipengliu mossderivedmesoporouscarbonasbifunctionalelectrodematerialsforlithiumsulfurbatteriesandsupercapacitors
AT junleixiao mossderivedmesoporouscarbonasbifunctionalelectrodematerialsforlithiumsulfurbatteriesandsupercapacitors
AT yangwang mossderivedmesoporouscarbonasbifunctionalelectrodematerialsforlithiumsulfurbatteriesandsupercapacitors
AT liangxulin mossderivedmesoporouscarbonasbifunctionalelectrodematerialsforlithiumsulfurbatteriesandsupercapacitors
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