catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]

catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]

In the title compound, {[Cu(C16H17FN3O3)2]·4H2O}n, the CuII atom is bonded to two O,O′-bidentate 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate (norf) monoanions and a symmetry-generated N-bonded norf anion, resulting in a distorted square-pyramidal c...

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Main Authors: Zhe An, Li-Xiang Duan, Xue-Ming Song, Shu-Ye Wang
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808026469
id doaj-4b863ce312ac45c28954d267b595fdd6
record_format Article
spelling doaj-4b863ce312ac45c28954d267b595fdd62020-11-24T21:30:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1201m120210.1107/S1600536808026469catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]Zhe AnLi-Xiang DuanXue-Ming SongShu-Ye WangIn the title compound, {[Cu(C16H17FN3O3)2]·4H2O}n, the CuII atom is bonded to two O,O′-bidentate 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate (norf) monoanions and a symmetry-generated N-bonded norf anion, resulting in a distorted square-pyramidal coordination environment with the N atom occupying the apical site. The bridging norf anion results in one-dimensional chains propogating along [010]. A network of O—H...O and N—H...O hydrogen bonds helps to establish the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808026469
collection DOAJ
language English
format Article
sources DOAJ
author Zhe An
Li-Xiang Duan
Xue-Ming Song
Shu-Ye Wang
spellingShingle Zhe An
Li-Xiang Duan
Xue-Ming Song
Shu-Ye Wang
catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
Acta Crystallographica Section E
author_facet Zhe An
Li-Xiang Duan
Xue-Ming Song
Shu-Ye Wang
author_sort Zhe An
title catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
title_short catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
title_full catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
title_fullStr catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
title_full_unstemmed catena-Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2O3,O4)copper(II)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3N7′:O3,O4] tetrahydrate]
title_sort catena-poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ2o3,o4)copper(ii)]-μ-1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato-κ3n7′:o3,o4] tetrahydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description In the title compound, {[Cu(C16H17FN3O3)2]·4H2O}n, the CuII atom is bonded to two O,O′-bidentate 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate (norf) monoanions and a symmetry-generated N-bonded norf anion, resulting in a distorted square-pyramidal coordination environment with the N atom occupying the apical site. The bridging norf anion results in one-dimensional chains propogating along [010]. A network of O—H...O and N—H...O hydrogen bonds helps to establish the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808026469
work_keys_str_mv AT zhean catenapoly1ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9542o3o4copperii9561ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9543n78242o3o4tetrahydrate
AT lixiangduan catenapoly1ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9542o3o4copperii9561ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9543n78242o3o4tetrahydrate
AT xuemingsong catenapoly1ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9542o3o4copperii9561ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9543n78242o3o4tetrahydrate
AT shuyewang catenapoly1ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9542o3o4copperii9561ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylato9543n78242o3o4tetrahydrate
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