[SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)

[SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)

The synthesis and crystal structure of the title PtII complex, [Pt(C23H16N)Cl(CH3CN)], based on the C,N-chelating 2,4,6-triphenylpyridine as the primary ligand, is described. The central PtII atom is in a distorted square-planar coordination environment. In the crystal, molecules are arranged via a...

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Bibliographic Details
Main Authors: Chengjian Fang, Zhao Wang, Zhongjian Cong, Shengli Li, Fei Li
Format: Article
Language:English
Published: International Union of Crystallography 2019-09-01
Series:IUCrData
Subjects:
crystal structure
platinum(II) complex
C,N-chelating ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619012070
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spelling doaj-4b8ae4373bd64f689417ec19bd5b21972020-11-24T21:48:24ZengInternational Union of CrystallographyIUCrData2414-31462019-09-0149x19120710.1107/S2414314619012070im4005[SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)Chengjian Fang0Zhao Wang1Zhongjian Cong2Shengli Li3Fei Li4Department of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaThe synthesis and crystal structure of the title PtII complex, [Pt(C23H16N)Cl(CH3CN)], based on the C,N-chelating 2,4,6-triphenylpyridine as the primary ligand, is described. The central PtII atom is in a distorted square-planar coordination environment. In the crystal, molecules are arranged via a metallophilic interaction between platinum atoms with a Pt...Pt contact of 7.052 (2) Å. In addition, a π–π interaction occurs.http://scripts.iucr.org/cgi-bin/paper?S2414314619012070crystal structureplatinum(II) complexC,N-chelating ligand
collection DOAJ
language English
format Article
sources DOAJ
author Chengjian Fang
Zhao Wang
Zhongjian Cong
Shengli Li
Fei Li
spellingShingle Chengjian Fang
Zhao Wang
Zhongjian Cong
Shengli Li
Fei Li
[SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
IUCrData
crystal structure
platinum(II) complex
C,N-chelating ligand
author_facet Chengjian Fang
Zhao Wang
Zhongjian Cong
Shengli Li
Fei Li
author_sort Chengjian Fang
title [SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
title_short [SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
title_full [SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
title_fullStr [SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
title_full_unstemmed [SP-4-2]-(Acetonitrile-κN)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2C1,N]platinum(II)
title_sort [sp-4-2]-(acetonitrile-κn)chlorido[2-(4,6-diphenylpyridin-2-yl)phenyl-κ2c1,n]platinum(ii)
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2019-09-01
description The synthesis and crystal structure of the title PtII complex, [Pt(C23H16N)Cl(CH3CN)], based on the C,N-chelating 2,4,6-triphenylpyridine as the primary ligand, is described. The central PtII atom is in a distorted square-planar coordination environment. In the crystal, molecules are arranged via a metallophilic interaction between platinum atoms with a Pt...Pt contact of 7.052 (2) Å. In addition, a π–π interaction occurs.
topic crystal structure
platinum(II) complex
C,N-chelating ligand
url http://scripts.iucr.org/cgi-bin/paper?S2414314619012070
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AT zhaowang sp42acetonitrileknchlorido246diphenylpyridin2ylphenylk2c1nplatinumii
AT zhongjiancong sp42acetonitrileknchlorido246diphenylpyridin2ylphenylk2c1nplatinumii
AT shenglili sp42acetonitrileknchlorido246diphenylpyridin2ylphenylk2c1nplatinumii
AT feili sp42acetonitrileknchlorido246diphenylpyridin2ylphenylk2c1nplatinumii
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