(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)

(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)

The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(NCC7H7)], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique RhII atom cis to one another...

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Bibliographic Details
Main Authors: Cassandra T. Eagle, Fredricka Quarshie, Kevin M. Cook
Format: Article
Language:English
Published: International Union of Crystallography 2014-08-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814016031
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spelling doaj-4c36d3101ff54ab6b02c223c0e180a2e2020-11-25T02:15:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-08-01708m304m30410.1107/S1600536814016031mw2125(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)Cassandra T. Eagle0Fredricka Quarshie1Kevin M. Cook2Department of Chemistry, East Tennessee State University, PO Box 70695, Johnson City, TN 37614, USADepartment of Chemistry, East Tennessee State University, PO Box 70695, Johnson City, TN 37614, USADepartment of Chemistry, East Tennessee State University, PO Box 70695, Johnson City, TN 37614, USAThe complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(NCC7H7)], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique RhII atom cis to one another. The Neq—Rh—Rh—Oeq torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octahedral coordination sphere of one RhII atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536814016031crystal structure
collection DOAJ
language English
format Article
sources DOAJ
author Cassandra T. Eagle
Fredricka Quarshie
Kevin M. Cook
spellingShingle Cassandra T. Eagle
Fredricka Quarshie
Kevin M. Cook
(3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
Acta Crystallographica Section E
crystal structure
author_facet Cassandra T. Eagle
Fredricka Quarshie
Kevin M. Cook
author_sort Cassandra T. Eagle
title (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
title_short (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
title_full (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
title_fullStr (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
title_full_unstemmed (3-Methylbenzonitrile-1κN)-cis-tetrakis(μ-N-phenylacetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)
title_sort (3-methylbenzonitrile-1κn)-cis-tetrakis(μ-n-phenylacetamidato)-1:2κ4n:o;1:2κ4o:n-dirhodium(ii)(rh—rh)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-08-01
description The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(NCC7H7)], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique RhII atom cis to one another. The Neq—Rh—Rh—Oeq torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octahedral coordination sphere of one RhII atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) Å.
topic crystal structure
url http://scripts.iucr.org/cgi-bin/paper?S1600536814016031
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AT kevinmcook 3methylbenzonitrile1kncistetrakismnphenylacetamidato12k4no12k4ondirhodiumiirhrh
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