Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands

Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands

The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, inc...

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Bibliographic Details
Main Authors: Zhang Lu-Lin, Tang Shi-Li, Li De-Jun, Cheng Yuan-Zheng, Zhang Li-Ping
Format: Article
Language:English
Published: De Gruyter 2021-06-01
Series:Main Group Metal Chemistry
Subjects:
lead(ii)
1,10-phenanthroline
4-nitrobenzoate
acetate
crystal structure
Online Access:https://doi.org/10.1515/mgmc-2021-0019
Description
Summary:The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.
ISSN:0792-1241
2191-0219

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