Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands
The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, inc...
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De Gruyter
2021-06-01
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| Series: | Main Group Metal Chemistry |
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| Online Access: | https://doi.org/10.1515/mgmc-2021-0019 |
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doaj-4cc75cb05d9040e485ec3b194d28e96b2021-10-03T07:42:38ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192021-06-0144115716410.1515/mgmc-2021-0019Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligandsZhang Lu-Lin0Tang Shi-Li1Li De-Jun2Cheng Yuan-Zheng3Zhang Li-Ping4School of Pharmacy, Weifang Medical University, Weifang261053, ChinaSchool of Pharmacy, Weifang Medical University, Weifang261053, ChinaSchool of Pharmacy, Weifang Medical University, Weifang261053, ChinaSchool of Pharmacy, Weifang Medical University, Weifang261053, ChinaSchool of Pharmacy, Weifang Medical University, Weifang261053, ChinaThe complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture.https://doi.org/10.1515/mgmc-2021-0019lead(ii)1,10-phenanthroline4-nitrobenzoateacetatecrystal structure |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping |
| spellingShingle |
Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands Main Group Metal Chemistry lead(ii) 1,10-phenanthroline 4-nitrobenzoate acetate crystal structure |
| author_facet |
Zhang Lu-Lin Tang Shi-Li Li De-Jun Cheng Yuan-Zheng Zhang Li-Ping |
| author_sort |
Zhang Lu-Lin |
| title |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| title_short |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| title_full |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| title_fullStr |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| title_full_unstemmed |
Synthesis and crystal structure of one new Pb(II) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| title_sort |
synthesis and crystal structure of one new pb(ii) complex constructed by 1,10-phenanthroline and two carboxylate ligands |
| publisher |
De Gruyter |
| series |
Main Group Metal Chemistry |
| issn |
0792-1241 2191-0219 |
| publishDate |
2021-06-01 |
| description |
The complex [Pb(phen)(4-NB)(CH3COO)] of lead(II) was prepared and characterized by means of elemental analysis, FT-IR, and single crystal X-ray analysis, where phen = 1,10-phenanthroline, 4-NB = 4-nitrobenzoate. The single crystal X-ray analysis indicates that the complex is a monomeric species, including two carboxylate ligands, and adopts a hemidirected structure. It is further extended by intermolecular C−H⋯O hydrogen bonds, π–π interactions and secondary Pb⋯O interactions to form two-dimensional supramolecular architecture. |
| topic |
lead(ii) 1,10-phenanthroline 4-nitrobenzoate acetate crystal structure |
| url |
https://doi.org/10.1515/mgmc-2021-0019 |
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