Crystal structure of di-μ-chlorido-bis[dichloridobis(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chloridoiridium(III) dinuclear complex with methanol ligands

Crystal structure of di-μ-chlorido-bis[dichloridobis(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chloridoiridium(III) dinuclear complex with methanol ligands

The reaction between IrCl3·xH2O in methanol led to the formation of small amounts of the title compound, [Ir2Cl6(CH3OH)4]·2H2O, which consists of two IrCl4O2 octahedra sharing an edge via chloride bridges. The molecule lies across an inversion center. Each octahedron can be envisioned as being compr...

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Bibliographic Details
Main Authors: Joseph S. Merola, Carla Slebodnick, Christopher Houser
Format: Article
Language:English
Published: International Union of Crystallography 2015-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iridium
chlorido bridge
methanol ligand
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015006672

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http://scripts.iucr.org/cgi-bin/paper?S2056989015006672

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