3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
In the title compound, C14H13N3OS2, the thiophene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the molecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxa...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812014419 |
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doaj-4cf9c95cf2584b99abf33d31369d76822020-11-24T21:28:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1345o134610.1107/S16005368120144193-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thioneTze Shyang ChiaHoong-Kun FunHazem A. GhabbourMohamed A. Al-OmarAli A. El-EmamIn the title compound, C14H13N3OS2, the thiophene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the molecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angles of 9.2 (5), 4.6 (11) and 47.70 (7)° with the major and minor parts of the disordered thiophene ring and the terminal phenyl ring, respectively. In the crystal, no significant intermolecular hydrogen bonds are observed. The crystal packing is stabilized by π–π interactions [centroid–centroid distance = 3.589 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812014419 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Tze Shyang Chia Hoong-Kun Fun Hazem A. Ghabbour Mohamed A. Al-Omar Ali A. El-Emam |
| spellingShingle |
Tze Shyang Chia Hoong-Kun Fun Hazem A. Ghabbour Mohamed A. Al-Omar Ali A. El-Emam 3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione Acta Crystallographica Section E |
| author_facet |
Tze Shyang Chia Hoong-Kun Fun Hazem A. Ghabbour Mohamed A. Al-Omar Ali A. El-Emam |
| author_sort |
Tze Shyang Chia |
| title |
3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione |
| title_short |
3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione |
| title_full |
3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione |
| title_fullStr |
3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione |
| title_full_unstemmed |
3-[(N-Methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3H)-thione |
| title_sort |
3-[(n-methylanilino)methyl]-5-(thiophen-2-yl)-1,3,4-oxadiazole-2(3h)-thione |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-05-01 |
| description |
In the title compound, C14H13N3OS2, the thiophene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the molecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angles of 9.2 (5), 4.6 (11) and 47.70 (7)° with the major and minor parts of the disordered thiophene ring and the terminal phenyl ring, respectively. In the crystal, no significant intermolecular hydrogen bonds are observed. The crystal packing is stabilized by π–π interactions [centroid–centroid distance = 3.589 (2) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812014419 |
| work_keys_str_mv |
AT tzeshyangchia 3nmethylanilinomethyl5thiophen2yl134oxadiazole23hthione AT hoongkunfun 3nmethylanilinomethyl5thiophen2yl134oxadiazole23hthione AT hazemaghabbour 3nmethylanilinomethyl5thiophen2yl134oxadiazole23hthione AT mohamedaalomar 3nmethylanilinomethyl5thiophen2yl134oxadiazole23hthione AT aliaelemam 3nmethylanilinomethyl5thiophen2yl134oxadiazole23hthione |
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1725968943854649344 |